Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Mikaela M. Pyrch"'
Publikováno v:
Dalton Transactions. 51:4772-4785
Actinyl-Actinyl interactions (AAIs) occur in pentavalent actinide systems, particularly for neptunium (Np), and lead to complex vibrational signals that are challenging to analyze and interpret. Previous studies have focused on neptunyl-neptunyl dime
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cf3a35f43cef45937f698732cf868820
https://doi.org/10.1039/d2dt00200k
https://doi.org/10.1039/d2dt00200k
Autor:
Jennifer L. Bjorklund, Daniel Parr, Sara E. Mason, Mikaela M. Pyrch, James M. Williams, Tori Z. Forbes, Johna Leddy
Publikováno v:
Dalton Transactions. 49:6854-6866
The neptunyl (Np(v)O2+/Np(vi)O22+) cation is the dominant form of 237Np in acidic aqueous solutions and the stability of the Np(v) and Np(vi) species is driven by the specific chemical constituents present in the system. Hydrogen bonding with the oxo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::771f44e6967e5f304e544c42c18bb3af
https://doi.org/10.1039/d0dt00848f
https://doi.org/10.1039/d0dt00848f
Autor:
Mikaela M, Pyrch, Jennifer L, Bjorklund, James M, Williams, Daniel L, Parr Iv, Sara E, Mason, Johna, Leddy, Tori Z, Forbes
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(20)
The neptunyl (Np(v)O
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::f5917ff7144df194897aced1a117ea59
https://pubmed.ncbi.nlm.nih.gov/32383725
https://pubmed.ncbi.nlm.nih.gov/32383725
Publikováno v:
Chemical Communications. 54:10828-10831
Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Diffe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::816b7fb6ff3f7d41f420cb9db479d1a8
https://doi.org/10.1039/c8cc05240a
https://doi.org/10.1039/c8cc05240a
Publikováno v:
Journal of Solid State Chemistry. 304:122619
Uranyl (U(VI)O22+) selenate compounds represent a well-studied family of structures with diverse structural arrays. Differences in the overall topology and bonding with the uranyl cation combined with additional intermolecular interactions can lead t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ba1bd266c2f5a1d130a7441179fde86e
https://doi.org/10.1016/j.jssc.2021.122619
https://doi.org/10.1016/j.jssc.2021.122619
Publikováno v:
Inorganic Chemistry. 56:9156-9168
The syntheses and crystal structures of six new heterometallic compounds containing the UO22+ cation, o-, m-, and p-iodobenzoic acid ligands, and Tl+, Rb+, and Cs+ cations which adopt the role of both charge balancing cation and secondary metal cente
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4fb9a686306beb72d1449108261b46bc
https://doi.org/10.1021/acs.inorgchem.7b01208
https://doi.org/10.1021/acs.inorgchem.7b01208
Publikováno v:
Chemical communications (Cambridge, England). 55(63)
Crown-ether molecules are used in radiochemical separations due to their high selectivity for a range of metal cations. Previous investigations regarding the interactions of 18-crown-6 (18C6) with 237Np suggested the formation of a Np(v) inclusion co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7489d479748ff4a2873136fe269bc79b
https://pubmed.ncbi.nlm.nih.gov/31313772
https://pubmed.ncbi.nlm.nih.gov/31313772
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 48(24)
The interaction of the actinyl (AnO
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::2a557a7dfb2ef26de0692272f3374c34
https://pubmed.ncbi.nlm.nih.gov/31139781
https://pubmed.ncbi.nlm.nih.gov/31139781
Publikováno v:
Polyhedron. 194:114904
Solvent extractions are used to separate actinide elements from fission products in nuclear waste streams and the successful isolation of specific species utilize subtle differences in metal ligand binding. Metal ligand binding is also important in c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7f7697ece13e38419f5edb64a644fea7
https://doi.org/10.1016/j.poly.2020.114904
https://doi.org/10.1016/j.poly.2020.114904
Autor:
Lindsey C. Applegate, Maguire W. Kasperski, Jay M. Williams, Mikaela M. Pyrch, Tori Z. Forbes
Publikováno v:
Inorganica Chimica Acta. 508:119628
A series of three new actinide tetrahalide coordination compounds containing 2,2′-bipyridinium (H2bpy) have been synthesized by room temperature evaporation and characterized via single crystal X-ray diffraction, Raman spectroscopy, and infrared sp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fcf351c3f6172b0ced8c80914ef9c92c
https://doi.org/10.1016/j.ica.2020.119628
https://doi.org/10.1016/j.ica.2020.119628