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Ion pairing has unexplored potential as a key catalyst-substrate interaction for controlling regioselectivity and site-selectivity in transition metal catalysis, particularly in the area of C-H activation. However, there is a significant perceived ch
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The elaboration of simple arenes in order to access more complex substitution patterns is a crucial endeavor for synthetic chemists, given the central role that aromatic rings play in all manner of important molecules. Classical methods are now routi
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https://www.repository.cam.ac.uk/handle/1810/273580
https://www.repository.cam.ac.uk/handle/1810/273580
Autor:
Mihai, MT, Phipps, RJ
We recently reported the use of ion pairing as a key noncovalent interaction to control regioselectivity in the iridium-catalyzed C–H borylation of aromatic quaternary ammonium salts. Two classes of substrates, benzylamine- and aniline-derived ammo
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The use of noncovalent interactions to direct transition-metal catalysis is a potentially powerful yet relatively underexplored strategy, with most investigations thus far focusing on using hydrogen bonds as the controlling element. We have developed
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https://explore.openaire.eu/search/publication?articleId=doi_dedup___::96d8c845bc427e879a7f17d6684c107d
Autor:
Lee B; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom., Mihai MT; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom., Stojalnikova V; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom., Phipps RJ; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom.
Publikováno v:
The Journal of organic chemistry [J Org Chem] 2019 Oct 18; Vol. 84 (20), pp. 13124-13134. Date of Electronic Publication: 2019 Jun 04.
Autor:
Mihai MT; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom., Williams BD; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom., Phipps RJ; Department of Chemistry , University of Cambridge , Lensfield Road , Cambridge CB2 1EW , United Kingdom.
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2019 Oct 02; Vol. 141 (39), pp. 15477-15482. Date of Electronic Publication: 2019 Sep 18.
Autor:
Davis HJ; Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge CB2 1EW, United Kingdom., Mihai MT; Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge CB2 1EW, United Kingdom., Phipps RJ; Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge CB2 1EW, United Kingdom.
Publikováno v:
Journal of the American Chemical Society [J Am Chem Soc] 2016 Oct 05; Vol. 138 (39), pp. 12759-12762. Date of Electronic Publication: 2016 Sep 21.