Zobrazeno 1 - 10
of 284
pro vyhledávání: '"Miguel A. Garcia‐Garibay"'
Publikováno v:
ACS Central Science, Vol 2, Iss 9, Pp 608-613 (2016)
Externí odkaz:
https://doaj.org/article/b855be6df0be418299483cbd5e9f0b80
Publikováno v:
Journal of the American Chemical Society. 145:1342-1348
Triplet acyl-alkyl radical pairs generated by pulsed laser excitation within the constraints of their nanocrystalline ketone precursors were recently introduced as a potential platform for the robust and repeated instantiation of spin qubit pairs for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4fa37dd89b83372b48ebaaf72112dea
https://doi.org/10.1021/jacs.2c11787
https://doi.org/10.1021/jacs.2c11787
Publikováno v:
Crystal Growth & Design. 22:1533-1537
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a3777e89d260be8feba80198298c0600
https://doi.org/10.1021/acs.cgd.1c01378
https://doi.org/10.1021/acs.cgd.1c01378
Autor:
Abel Carreras, Andreas Lorbach, Guillermo C. Bazan, Pere Alemany, Guang Wu, Miguel A. Garcia‐Garibay, Emily F. Maverick
Publikováno v:
Helvetica Chimica Acta. 106
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::258ad277d1acdb3c36ece7666f27d3c8
https://doi.org/10.1002/hlca.202200142
https://doi.org/10.1002/hlca.202200142
Publikováno v:
The Journal of Organic Chemistry. 87:1780-1790
Artificial molecular machines are expected to operate in environments where viscous forces impact molecules significantly. With that, it is well-known that solvent behaviors dramatically change upon confinement into limited spaces as compared to bulk
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fbf593fb4506d4268d16b1526d8236b8
https://doi.org/10.1021/acs.joc.1c02218
https://doi.org/10.1021/acs.joc.1c02218
Publikováno v:
The Journal of Physical Chemistry Letters. 12:5644-5648
A zirconium metal-organic framework with a difluorophenylene rotator bearing a permanent electric dipole of ∼3.2 D was synthesized, and its rotational motion was analyzed by temperature- and frequency-dependent broadband dielectric spectroscopy. Wh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b38ad6a0e0b39b337f760f89416d2e49
https://doi.org/10.1021/acs.jpclett.1c01333
https://doi.org/10.1021/acs.jpclett.1c01333
Publikováno v:
Journal of the American Chemical Society. 143:8886-8892
Radical pairs generated in crystalline solids by bond cleavage reactions of triplet ketones offer the unique opportunity to explore a frontier of spin dynamics where rigid radicals are highly entangled as the result of short inter-radical distances,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7cfc86d46d1ffe95f7716ee2aa0d15f7
https://doi.org/10.1021/jacs.1c03026
https://doi.org/10.1021/jacs.1c03026
Taming Radical Pairs in the Crystalline Solid State: Discovery and Total Synthesis of Psychotriadine
Autor:
Neil K. Garg, Ieva Liepuoniute, Miguel A. Garcia-Garibay, Vince M. Hipwell, Saeed I. Khan, Kendall N. Houk, J. Logan Bachman, Jordan J. Dotson
Publikováno v:
J Am Chem Soc
Solid-state photodecarbonylation is an attractive but underutilized methodology to forge hindered C−C bonds in complex molecules. This study discloses the use of this reaction to assemble the vicinal quaternary stereocenter motif present in bis(cyc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94daed37bcec3413d304fb3310d206c3
https://doi.org/10.1021/jacs.1c01100
https://doi.org/10.1021/jacs.1c01100
Autor:
Salvador Pérez-Estrada, Trevor Y Chang, Ieva Liepuoniute, A. L. Stanton, Yue-Shun Su, K. N. Houk, P. Guzman, Miguel A. Garcia-Garibay, E. S. Lamb, A. Chronister, Stuart Brown
Publikováno v:
Nature Chemistry. 13:278-283
Amphidynamic crystals, which possess crystallinity and support dynamic behaviours, are very well suited to the exploration of emergent phenomena that result from the coupling on the dynamic moieties. Here, dipolar rotors have been embedded in a cryst
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::33c6ddb01e027bd79117aafac81df784
https://doi.org/10.1038/s41557-020-00618-6
https://doi.org/10.1038/s41557-020-00618-6
Publikováno v:
Organic Letters. 22:8855-8859
We report the synthesis and stereospecific solid-state photodecarbonylation of a hexasubstituted ketone featuring six distinct α-substituents. The photoproduct of the solid-state transformation features vicinal all-carbon quaternary stereocenters. W
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c0fec97880dc361a7e94be00d6f8c00f
https://doi.org/10.1021/acs.orglett.0c03226
https://doi.org/10.1021/acs.orglett.0c03226