Zobrazeno 1 - 10 of 512 pro vyhledávání: '"Miguel A. Esteruelas"'
1
Synthesis, Structure, and Photophysical Properties of Platinum(II) (N,C,N′) Pincer Complexes Derived from Purine Nucleobases
Autor: Carmen Lorenzo-Aparicio, Sonia Moreno-Blázquez, Montserrat Oliván, Miguel A. Esteruelas, Mar Gómez Gallego, Pablo García-Álvarez, Javier A. Cabeza, Miguel A. Sierra
Publikováno v: Inorganic Chemistry. 62:8232-8248
The synthesis of a series of Pt{κ3-N,C,N′-[L]}X (X = Cl, RC≡C) pincer complexes derived from purine and purine nucleosides is reported. In these complexes, the 6-phenylpurine skeleton provides the N,C-cyclometalated fragment, whereas an amine, i
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e17c746b0acb7943600b623ab8f8c90
https://doi.org/10.1021/acs.inorgchem.3c00650
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2
Encapsulated-Type Iridium(III) Phosphorescent Emitters with a Hexadentate Ligand of Three Different Bidentate Units
Autor: Llorenç Benavent, Pierre-Luc T. Boudreault, Miguel A. Esteruelas, Ana M. López, Enrique Oñate, Jui-Yi Tsai
Publikováno v: Organometallics. 42:871-875
The preparation and photophysical properties of new phosphorescent iridium(III) emitters are reported. The metal center is encapsulated by a hexadentate ligand made up of three different bidentate fragments: orthometalated 2-phenylpyridine, orthometa
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4e36d410795780beb30334ad1aa9a060
https://doi.org/10.1021/acs.organomet.3c00158
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3
Ligand Design and Preparation, Photophysical Properties, and Device Performance of an Encapsulated-Type Pseudo-Tris(heteroleptic) Iridium(III) Emitter
Autor: Vadim Adamovich, Llorenç Benavent, Pierre-Luc T. Boudreault, Miguel A. Esteruelas, Ana M. López, Enrique Oñate, Jui-Yi Tsai
Publikováno v: Inorganic Chemistry. 62:3847-3859
The organic molecule 2-(1-phenyl-1-(pyridin-2-yl)ethyl)-6-(3-(1-phenyl-1-(pyridin-2-yl)ethyl)phenyl)pyridine (H3L) has been designed, prepared, and employed to synthesize the encapsulated-type pseudo-tris(heteroleptic) iridium(III) derivative Ir(κ6-
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::31b01b9410637416cd3b1eae5c79d152
https://doi.org/10.1021/acs.inorgchem.2c04106
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4
Silyl-Osmium(IV)-Trihydride Complexes Stabilized by a Pincer Ether-Diphosphine: Formation and Reactions with Alkynes
Autor: Juan C. Babón, Miguel A. Esteruelas, Enrique Oñate, Sonia Paz, Andrea Vélez
Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Complex OsH4{κ3-P,O,P-[xant(PiPr2)2]} (1) activates the Si–H bond of triethylsilane, triphenylsilane, and 1,1,1,3,5,5,5-heptamethyltrisiloxane to give the silyl-osmium(IV)-trihydride derivatives OsH3(SiR3){κ3-P,O,P-[xant(PiPr2)2]} [SiR3 = SiEt3 (
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c60ec967783b4f000d4e0b5ddd0e186
https://doi.org/10.1021/acs.organomet.2c00201
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5
Osmathiazole ring: Extrapolation of an aromatic purely organic system to organometallic chemistry
Autor: María L. Buil, Miguel A. Esteruelas, Enrique Oñate, Nieves R. Picazo
An osmathiazole skeleton has been generated starting from the cation of the salt [OsH(OH)(≡CPh)(IPr)(PiPr3)]OTf (1; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolylidene; OTf = CF3SO3) and thioacetamide; its aromaticity degree was compared with that
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4959c22131eeef8c75a52f4859a5b630
http://hdl.handle.net/10261/296093
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6
Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid
Autor: Carlos J. Laglera-Gándara, Enrique Oñate, María L. Buil, Miguel A. Esteruelas, Susana Izquierdo, Antonio I. Nicasio, Javier A. Cabeza
Publikováno v: Inorganic Chemistry
Scopus
RUO. Repositorio Institucional de la Universidad de Oviedo
Universidad de las Islas Baleares
Digital.CSIC. Repositorio Institucional del CSIC
instname
The reaction of the hexahydride OsH6(PiPr3)2 with a P,Ge,P-germylene-diphosphine affords an osmium tetrahydride derivative bearing a Ge,P-chelate, which arises from the hydrogenolysis of a P–C(sp3) bond. This Os(IV)–Ge(II) compound is a pioneerin
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1674bcecae131b686d45ede73b60e3f4
http://europepmc.org/articles/PMC8564761
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8
Homogeneous catalysis with polyhydride complexes
Autor: Juan C. Babón, Miguel A. Esteruelas, Ana M. López
Publikováno v: Chemical Society reviews. 51(23)
Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride complexes, LnMHx (x ≥ 3), are analyzed for about forty types of organic reactions catalyzed by such class of species. Reactions involve nearly every main organ
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d10919bfa1d2113c90055fdefe7c24c0
https://pubmed.ncbi.nlm.nih.gov/36350069
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9
Metathesis between E−C(sp n ) and H−C(sp 3 ) σ‐Bonds (E=Si, Ge; n =2, 3) on an Osmium‐Polyhydride
Autor: Miguel A. Esteruelas, Ana M. López, Enrique Oñate, Esther Raga
Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
The silylation of a phosphine of OsH6(PiPr3)2 is performed via net-metathesis between Si−C(spn) and H−C(sp3) σ-bonds (n=2, 3). Complex OsH6(PiPr3)2 activates the Si−H bond of Et3SiH and Ph3SiH to give OsH5(SiR3)(PiPr3)2, which yield OsH4{κ1-P
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::81f738ecc62599a0e9d9300d60992787
https://doi.org/10.1002/ange.202204081
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