Výsledky vyhledávání - "Miguel Ángel Rivero-Crespo"

Akademický článek

Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

Autor: Vicent Lloret, Miguel Ángel Rivero-Crespo, José Alejandro Vidal-Moya, Stefan Wild, Antonio Doménech-Carbó, Bettina S. J. Heller, Sunghwan Shin, Hans-Peter Steinrück, Florian Maier, Frank Hauke, Maria Varela, Andreas Hirsch, Antonio Leyva-Pérez, Gonzalo Abellán

Publikováno v: Nature Communications, Vol 10, Iss 1, Pp 1-11 (2019)

Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero ox

Externí odkaz: https://doaj.org/article/28a596c09abf4115927d5c20f93f25ca

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Acid Catalysis with Alkane/Water Microdroplets in Ionic Liquids

Autor: Gonzalo Abellán, Antonio Doménech-Carbó, Andreas Hirsch, Miguel Ángel Rivero-Crespo, Vicent Lloret, Rossella Greco, Antonio Leyva-Pérez

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Abellán Sáez, Gonzalo, et. al. 2021. Acid Catalysis with Alkane/Water Microdroplets in Ionic Liquids. JACS
RODERIC: Repositorio Institucional de la Universitat de Valéncia
Universitat de València
JACS Au
JACS Au, Vol 1, Iss 6, Pp 786-794 (2021)
Jacs Au
RODERIC. Repositorio Institucional de la Universitat de Valéncia

Ionic liquids are composed of an organic cation and a highly delocalized perfluorinated anion, which remain tight to each other and neutral across the extended liquid framework. Here we show that n-alkanes in millimolar amounts enable a sufficient io

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::512711bdf5a5a470e204441a72b85e53
https://doi.org/10.1021/jacsau.1c00107

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Preparation of Recyclable and Versatile Porous Poly-Arylthioethers by Reversible Pd-Catalysed C–S/C–S Metathesis

Autor: Bill Morandi, Miguel Ángel Rivero-Crespo, Georgios Toupalas

Porous organic polymers have shown a number of promising properties; however, their application is usually hampered due to the lability of their linkages. Inspired by the outstanding chemical, mechanical and thermal resistance of the 1D polymer polyp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::829da26bfe34fab9b370c11ac04b152a
https://doi.org/10.26434/chemrxiv-2021-h28j4-v2

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Gitteröffnung durch reduktive kovalente Volumen‐Funktionalisierung von schwarzem Phosphor

Autor: Herwig Peterlik, Christian Papp, Haiko Wittkämper, Andreas Görling, Stefan Wild, Mathias Grabau, Miguel Ángel Rivero-Crespo, Antonio Leyva-Pérez, Frank Hauke, Aleksandra Mitrovic, Hans-Peter Steinrück, Katharina Werbach, Michael Fickert, Christian Neiss, Gonzalo Abellán, Thomas Pichler, Vicent Lloret, Andreas Hirsch, Jose A. Vidal-Moya

Publikováno v: RODERIC. Repositorio Institucional de la Universitat de Valéncia
instname
RODERIC: Repositorio Institucional de la Universitat de Valéncia
Angewandte Chemie

Eine chemisch-reduktive Volumen-Funktionalisierung von dünnlagigem schwarzem Phosphor (BP) gelang unter Verwendung von BP-Interkalationsverbindungen. Durch eine effektive reduktive Aktivierung wurde die kovalente Funktionalisierung des geladenen BP

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4d64c4c6274cc0672d647bba618df18c
https://doi.org/10.1002/ange.201811181

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Preparation of Versatile, Porous Poly-Arylthioethers by Reversible Pd-Catalysed C–S/C–S Metathesis

Autor: Miguel Ángel Rivero-Crespo, Bill Morandi, Georgios Toupalas

Porous organic frameworks have shown a number of promising properties; however, their industrial application is usually hampered due to the lability of their linkages (imine, boroxine, etc.). Inspired by the outstanding chemical, mechanical and therm

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2de71acd5212deca5b10d77d4f9b6c60
https://doi.org/10.26434/chemrxiv.14075390

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Intermolecular Carbonyl-olefin Metathesis with Vinyl Ethers Catalyzed by Homogeneous and Solid Acids in Flow

Autor: Horacio Pérez-Sánchez, José P. Cerón-Carrasco, Antonio Leyva-Pérez, Miguel Ángel Rivero-Crespo, María Tejeda-Serrano

Publikováno v: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname
Digital.CSIC. Repositorio Institucional del CSIC

[EN] The carbonyl-olefin metathesis reaction has experienced significant advances in the last seven years with new catalysts and reaction protocols. However, most of these procedures involve soluble catalysts for intramolecular reactions in batch. He

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::33f9cb57c0e90e3c9b36fa16bdb1a211

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Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions : from soluble to zeolite and MOF catalysts

Autor: Judit Oliver-Meseguer, Antonio Leyva-Pérez, Emilio Pardo, Piotr Kuśtrowski, José P. Cerón-Carrasco, Klaudia Kapłońska, Miguel Ángel Rivero-Crespo

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
Chemical Science
Chemical Science, 11 (31)

The Pt-catalysed addition of silanes to functional groups such as alkenes, alkynes, carbonyls and alcohols, i.e. the hydrosilylation reaction, is a fundamental transformation in industrial and academic chemistry, often claimed as the most important a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59cc4de131ad9c04f63c85923b94e450
https://ruj.uj.edu.pl/xmlui/handle/item/251136

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Nanoceria as a recyclable catalyst/support for the cyanosilylation of ketones and alcohol oxidation in cascade

Autor: Francisco Garnes-Portolés, Miguel Ángel Rivero-Crespo, Antonio Leyva-Pérez

Publikováno v: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname
Digital.CSIC. Repositorio Institucional del CSIC

[EN] The cyanosilylation of carbonyl compounds is a fundamental reaction in organic synthesis, to give cyanohydrins. Ketones are particularly reluctant to cyanosilane addition and require the action of a catalyst, and despite many soluble Bronsted an

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d3eaa1d7d352d0ded381291c03cd816a
http://hdl.handle.net/10251/182986

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A Ligand-Free Pt3Cluster Catalyzes the Markovnikov Hydrosilylation of Alkynes with up to 106Turnover Frequencies

Autor: Antonio Leyva-Pérez, Miguel Ángel Rivero-Crespo, Avelino Corma

Publikováno v: RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname

[EN] The Pt-catalyzed hydrosilylation of alkynes is the procedure of choice to obtain vinylsilanes, and is claimed to be the most relevant application of Pt in organic synthesis. More than half a century after its discovery, only b-vinylsilanes (anti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9803b994eda3bf6cc73553802391e63d
https://doi.org/10.1002/chem.201605520

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