Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Michiel C. A. van Vliet"'
Autor:
Leo Jacques Pierre Van Den Broeke, Berth-Jan Deelman, Ard C. J. Koeken, Michiel C. A. van Vliet, Jos T. F. Keurentjes
Publikováno v:
Advanced Synthesis & Catalysis, 350(1), 179-188. Wiley-VCH Verlag
The regioselectivity of catalysts generated in situ from dicarbonyl rhodium(I)(2,4-pentanedione) and trifluoromethyl-substituted triphenylphosphine ligands has been evaluated during the hydroformylation of 1-octene. The influence of batch or semi-bat
Publikováno v:
Applied Catalysis A: General. 219:209-213
Inexpensive Al 2 O 3 can be used as a simple catalyst for alkene epoxidation, using anhydrous hydrogen peroxide as oxidant. This system is active and selective in the epoxidation of several alkenes. Besides the epoxidation of the terpenes limonene an
Autor:
Dalmo Mandelli, Roger A. Sheldon, Michiel C. A. van Vliet, Ulf Schuchardt, Isabel W. C. E. Arends
Publikováno v:
Green Chemistry. 3:243-246
Chromatography alumina catalyses the epoxidation of alkenes with hydrogen peroxide under nearly anhydrous conditions. A variety of different aluminas show a similar catalytic behaviour. The hydrogen peroxide can be used as a preformed anhydrous solut
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 168:165-171
Rhenium oxides supported on zeolite Y, mixed silica–alumina and pure alumina were prepared by impregnation of the supports with Re 2 O 7 or NH 4 ReO 4 . The materials are active catalysts in the epoxidation of cyclooctene and cyclohexene with anhyd
Autor:
Gerd-Jan ten Brink, Bruno C. M. Fernandes, Michiel C. A. van Vliet, Isabel W. C. E. Arends, Roger A. Sheldon
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :224-228
Several diselenides were synthesised and tested for catalytic activity in epoxidation reactions with aqueous hydrogen peroxide. Bis[3,5-bis(trifluoromethyl)phenyl] diselenide forms the corresponding 3,5-bis(trifluoromethyl)benzene seleninic acid (L.
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :377-380
Perrhenic acid in combination with tertiary arsines gives a versatile catalytic system for epoxidation of alkenes with hydrogen peroxide. The best results are obtained with diphenylmethylarsine. A wide range of alkenes could be epoxidised with aqueou
Publikováno v:
European Journal of Organic Chemistry. 1999:2315-2321
The chiral 1,2,3,4-tetrahydroisoquinoline intermediates in the Rice and Beyerman routes to morphine, (+)-(R)-1-(3-hydroxy-4-methoxybenzyl)-6-methoxy-1,2,3,4-tetrahydroisoquinoline (6) and (+)-(R)-1-(3,5-dibenzyloxy-4-methoxybenzyl)-6-methoxy-1,2,3,4-
Publikováno v:
Tetrahedron Letters. 40:5239-5242
Tertiary arsines are active and selective catalysts for the epoxidation of a variety of alkenes with hydrogen peroxide at low catalyst loading (1–5 mol%); highly fluorinated analogues of these arsines can be recovered and reused with moderate effic
Publikováno v:
Liebigs Annalen. 1997:1989-1995
γ,δ-Unsaturated N-formylenamines (5–7) were prepared in two steps from readily available γ,δ-unsaturated alcohols. The alcohols were converted into the γ,δ-unsaturated diformamides (N,N-diformylamines, 1–4) by tosylation, followed by reacti
Autor:
Ernst Neeleman, Michiel C. A. van Vliet, Roger A. Sheldon, Leendert Maat, Gerrit J. Meuzelaar
Publikováno v:
Liebigs Annalen. 1997:1159-1163
N-Formyl-N-styryl amines (1–3) were prepared from imines derived from γ-unsaturated amines and phenylacetaldehyde by formylation with ethyl formate in the presence of sodium methoxide. Formation of the corresponding N-acetyl analogues was less sel