Zobrazeno 1 - 10
of 51
pro vyhledávání: '"Michel Guelton"'
Publikováno v:
Chemistry of Materials. 17:2369-2377
Sol-gel boria-alumina mixed oxides with a wide range of B / Al atomic compositions have been characterized as dried xerogels in the preceding paper in which a structural model with four domains of composition was proposed. The present paper presents
Publikováno v:
Chemistry of Materials. 17:2361-2368
While boria-alumina mixed oxides have been widely used for various catalytic reactions, their structure has never been satisfactory elucidated and is still a matter of debates. The present paper deals with the elucidation of the structure of boria-al
Autor:
R. Mezzogori, G Calestani, Michel Guelton, E. Etienne, F. Trifirò, Fabrizio Cavani, Léon Gengembre
Publikováno v:
Applied Catalysis A: General. 256:275-290
Iron-doped, ammonium/potassium salts of 12-molybdophosphoric acid (Keggin-type polyoxometalates (POMs)) were prepared, characterized and tested as catalysts for the selective oxidation of isobutane to methacrylic acid. In samples calcined at 623 K, i
Autor:
Jean-Paul Amoureux, Michel Fournier, Subramanian Ganapathy, Michel Guelton, Laurent Delevoye, Jean-François Paul
Publikováno v:
Journal of the American Chemical Society. 124:7821-7828
HeteroPolyAcids (HPA's) are a class of solid acids that have broad applications in many fields of science and technology, including catalysis and chemical engineering. The proton locations within the thermally stable and commonly known Keggin unit, w
Autor:
Renaud Cousin, Antoine Aboukaïs, Jean-Paul Amoureux, M. Dourdin, Michel Guelton, Edmond Abi-Aad, Dominique Courcot, S. Capelle
Publikováno v:
Colloids and Surfaces A: Physicochemical and Engineering Aspects. 158:43-49
Vanadium–cerium oxide samples with different V/Ce atomic ratios were prepared using the impregnation method, and then calcined under air at 773 K, and characterized by XRD and 51V MAS NMR. Ceria is the only phase evidenced in low vanadium content s
Autor:
Christian Fernandez, Jean-Paul Amoureux, Jean Grimblot, Monique Rigole, Michel Guelton, Franck Dumeignil
Publikováno v:
Colloids and Surfaces A: Physicochemical and Engineering Aspects. 158:75-81
Boria–alumina mixed oxides were synthesized by the sol-gel method. MAS-NMR spectroscopy spectra exhibited two boron species, BO 3 and BO 4 , the former giving an important second order quadrupolar effect. Then, spectra were interpreted with a simul
Publikováno v:
Journal de Chimie Physique et de Physico-Chimie Biologique. 96:1536-1542
La RMN du solide et notamment la methode « MQMAS » de 27 Al est utilisee pour caracteriser en detail les catalyseurs d'hydrotraitement du type Mo-P-Al sous forme oxyde. Cette application montre que la RMN est un outil efficace pour determiner la st
Autor:
Emilie Blouet-Crusson, Gérard Hecquet, Michel Fournier, Michel Guelton, Franck Daubrege, Monique Rigole, Antoine Aboukaïs
Publikováno v:
Applied Catalysis A: General. 178:69-83
The oxidative dehydrogenation of isobutyric acid (IBA) to methacrylic acid (MAA) has been studied over cupric salts of undecamolybdovanadophosphoric acid CuxH4−2xPVMo11O40. The presence of copper as counter cation in heteropoly compounds increases
Autor:
Monique Rigole, Michel Guelton, Christian Fernandez, Jean-Paul Amoureux, Jean Grimblot, Juliette Quartararo
Publikováno v:
Journal of Materials Chemistry. 9:2637-2646
A sol–gel method using aluminium tri(sec-butoxide) and orthophosphoric acid, H 3 PO 4 , as the Al and P sources respectively, 2-butanol as the solvent and 1,3-butanediol as the chelating agent has been extensively used to prepare P-alumina catalyti
Autor:
Jean Grimblot, S. Pietrzyk, Michel Guelton, Léon Gengembre, Faustin C. Aïssi, and Ahmed Latef, Trino Romero, Abdès El Gharbi, Ginette Leclercq, Lucien Leclercq
Publikováno v:
Industrial & Engineering Chemistry Research. 36:4015-4027
A series of bimetallic catalysts Pt−Mo deposited on silica, with the same (Pt + Mo) metal atom content but various Mo/Mo + Pt ratios, has been synthesized and characterized by XPS, ESR, hydrogen chemisorption, and oxygen uptake during their reoxida