Zobrazeno 1 - 10
of 210
pro vyhledávání: '"Michel Boudart"'
Autor:
John R. Anderson, Michel Boudart
For catalytic practitioners who are concerned with laboratory studies of reaction mechanisins, as often as not catalyst deactivation is· treated as a nuisance to be ignored or factored out of the experimental results. How ever, the engineer concer
Autor:
Michel Boudart
Publikováno v:
Topics in Catalysis. 14:181-185
Chemical kinetics makes it possible to discuss catalysis without chemistry. The general kinetic rules lead to generalities concerning catalytic mechanisms including rate constants, their impact on the turnover frequency of the cycle, product inhibiti
Autor:
Michel Boudart
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 141:1-7
Adsorption assisted desorption is an important phenomenon in catalytic cycles. It takes place when a desorption step is not equilibrated. The surface concentration or fugacity of the desorbing species can be higher than its equilibrium value because
Autor:
John R. Anderson, Michel Boudart
Catalytic steam reforming has grown during the last two or three decades into one of the world's great catalytic processes. It is of major economic significance since the products from it form the feed for a number of other major processes. Neverthel
Autor:
John R. Anderson, Michel Boudart
The development of a commercially successful process for the catalytic synthesis of ammonia was a scientific as well as a technical triumph. Its implications were con siderable. It demonstrated the power of a combination of innovative technology an
Autor:
Michel Boudart
Publikováno v:
Chemical Reviews. 95:661-666
Publikováno v:
Catalysis Letters. 31:411-420
With an oxygen containing molybdenum nitride catalyst, the rate of hydrogenation of propylbenzene increases with time. This is attributed to the carburization of surface during reaction. Both surface reactivity in chemisorption and superficial chemic
Autor:
Michel Boudart
Publikováno v:
Industrial & Engineering Chemistry Research. 33:2900-2903
Thermodynamic and kinetic problems are examined, as encountered in the design of catalytic devices for the removal of pollutants in the ppm range, i.e., for ultrapuribcation. The customary approximations used in catalytic reaction engineering are exa
Autor:
Robert J. Davis, Michel Boudart
Publikováno v:
The Journal of Physical Chemistry. 98:5471-5477
The extended X-ray absorption fine structure (EXAFS) above the Pd K and Au L[sub III] edges and the X-ray absorption near edge structure (XANES) associated with the Au L[sub III] edge were used to study the structure and local electronic environment
Publikováno v:
Catalysis Letters. 29:7-13
Quasi-equilibrium between catalytic reactive intermediates and reactant or product molecules is a common assumption. As process conditions vary, this assumption may cease to be valid because of kinetic coupling between steps in the catalytic cycle. I