Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Michel Barrelle"'
Publikováno v:
Tetrahedron: Asymmetry. 7:1961-1966
The title compound was found to be useful as a chiral derivating agent in 19 F NMR spectroscopy, to determine the enantiomeric purity of 2,2′-dihydroxybinaphtyl and its monoether derivatives. The configurations of ether derivatives are easily deduc
Autor:
Michel Barrelle
Publikováno v:
Journal of Wood Chemistry and Technology. 15:179-188
Derivatization of lignins samples by p-fluorobenzyl groups (etherification of phenolic groups) leads to the distinction between G and G-S-lignin, and to analyze approximately the G/S ratio and the (α −C=O) content of the studied samples by integra
Autor:
Michel Barrelle
Publikováno v:
hfsg. 47:261-267
Publikováno v:
Journal of Wood Chemistry and Technology. 12:413-424
Derivatization of an oxidized lignin sample by suitable fluoroaromatic compounds is described. Integration of the 19F NMR spectra of the derivatives allows the determination of the carboxyl content of the sample. Three reagents were investigated : 4-
Autor:
Sylvain Hamman, Michel Barrelle
Publikováno v:
Magnetic Resonance in Chemistry. 29:759-761
The use of 2-fluoro-2-phenylacetic acid as a chiral derivatizing agent allowed the distinction, by means of fluorine NMR spectroscopy, of enantiomers of alcohols L1CH(OH)L2 converted into the diastereoisomeric esters PhCHFCO2CHL1L2. The δF(RR) and
Autor:
Michel Barrelle, Marcel Apparu
Publikováno v:
Tetrahedron Letters. 17:2611-2614
Publikováno v:
Journal of Fluorine Chemistry. 37:85-94
2-Fluoro-2-phenyl acetic acid was synthetized from phenylglycine through a fluorodeamination reaction in a HF : pyridine mixture or from ethylmandelate through fluorodehydroxylation using the reagent fluoroamine (FAR). The specific rotation of S-2-fl
Autor:
Jean Pelmont, Anastase Dardas, Dominique Gal, Ginette Sauret-Ignazi, Michel Barrelle, Raja Sterjiades
Publikováno v:
Archives of Biochemistry and Biophysics. 236:585-592
Spectroscopic studies were carried with a cytochrome P-450 in Moraxella sp., strain GU2, that could grow on guaiacol or 2-ethoxyphenol as the sole source of carbon and energy. The dissociation constant of the guaiacol-cytochrome complex was estimated
Publikováno v:
Holzforschung. 43:339-343
The stereochemical pathway of the hybride reductions of lignin model compounds (ketoalcohols and ketoesters) was studied in different conditions to obtain a complete information on the erythro/threo ratios, during synthesis of guaiacylglycerol-guaiac
Publikováno v:
Organic Magnetic Resonance. 19:102-104
The 13C NMR spectra of several oligo(oxyethylene) glycols and of their derivatives obtained from oxidative cleavage were studied. Assignments are proposed and the 13C chemical shifts recalculated from sets of parameters obtained for the substituents