Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Michael T.H. Liu"'
Publikováno v:
The Journal of Physical Chemistry A. 108:1312-1318
The analysis of the time-resolved UV-vis absorption spectra of the 2-vinylpyridinium ylide of phenylchlorocarbene, measured by laser-flash photolysis, indicates the existence of two rotamers of this species. The absorption spectrum, rise time, and de
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b9d7075c07b45e921afe55250c8a4a7d
https://doi.org/10.1021/jp030991d
https://doi.org/10.1021/jp030991d
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 161:43-50
The photolysis of m -phenylene-bis(chlorodiazirine) in the presence of 2-vinylpyridine (VP) yields the m -phenylene-bis(indolizine) by a mechanism involving two consecutive photoreactions. Photolysis of a first diazirine ring generates a carbene whic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f82a2125ff62676e54c60f646f5209d7
https://doi.org/10.1016/s1010-6030(03)00269-7
https://doi.org/10.1016/s1010-6030(03)00269-7
Publikováno v:
Canadian Journal of Chemistry. 77:540-549
The reactions of the singlet methylene (1a) and dimethylcarbene (1b), with their diazirine precursors, diazirine (2a), and dimethyldiazirine (2b), have been studied theoretically using ab initio and density functional theory. The reaction has no acti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f7051f75623c830f6895daf29c14cbc6
https://doi.org/10.1139/v99-012
https://doi.org/10.1139/v99-012
Publikováno v:
Canadian Journal of Chemistry. 76:1162-1173
An ultraviolet photoelectron (PE) spectrometer apparatus that utilizes a tuneable 50 W CW CO2 laser as a directed heat source was used to study the vacuum pyrolysis of diazoacetophenone (1a) and its p-methyl, p-methoxy, p-chloro, and p-nitro analogue
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a5fb83a3932bf3aa14fbabc592fc373e
https://doi.org/10.1139/v98-127
https://doi.org/10.1139/v98-127
Autor:
Gennady V. Shustov, Michael T.H. Liu
Publikováno v:
Canadian Journal of Chemistry. 76:851-861
Rearrangements of 2-adamantene 3, adamantylidene 4, and 4-protoadamantylidene 5 have been studied theoretically using high level ab initio computations. Adamantene 3 and adamantylidene 4 have singlet ground states. The conversion of 3 into 4 via 1,2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1124ef798c8ad5cddfecea2d332c9b09
https://doi.org/10.1139/v98-078
https://doi.org/10.1139/v98-078
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 116:9-19
Irradiation of 2-adamantane-2,3′-[3 H ]-diazirine ( 1 ) in isooctane at room temperature gives two primary photoproducts, 2-diazoadamantane and 2-adamantylidene ( Ad: ), with quantum yields of about 0.5 each. The fluorescence quantum yield of 1 is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9baa4cce3ce83020f4bf58e720a6bc6c
https://doi.org/10.1016/s1010-6030(98)00288-3
https://doi.org/10.1016/s1010-6030(98)00288-3
Autor:
Masaaki Mishima, Shinjiro Kobayashi, Takatsugu Matsumoto, Michael T.H. Liu, Gennady V. Shustov
Publikováno v:
ChemInform. 29
N-Protonated diazomethanes have been generated successfully via gas phase protonation of the corresponding diazirines.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2cd13cf69daacc3b23d9572ddeeeeb4a
https://doi.org/10.1002/chin.199846102
https://doi.org/10.1002/chin.199846102
Autor:
Shinjiro Kobayashi, Gennady V. Shustov, Takatsugu Matsumoto, Masaaki Mishima, Michael T.H. Liu
Publikováno v:
Chemical Communications. :1655-1656
N-Protonated diazomethanes have been generated successfully via gas phase protonation of the corresponding diazirines.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9bc63e7077525baa1fd806336c629a16
https://doi.org/10.1039/a802640h
https://doi.org/10.1039/a802640h
Publikováno v:
Tetrahedron Letters. 27:4395-4398
Non-concerted addition of arylchlorocarbenes to diethyl maleate, accompanied by isomerization of maleate to fumarate, is consistent with an intermediate carbene—alkene dipolar adduct.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::20165a64a1cdce997e650a16ae521efc
https://doi.org/10.1016/s0040-4039(00)84961-8
https://doi.org/10.1016/s0040-4039(00)84961-8
Publikováno v:
ChemInform. 18
Non-concerted addition of arylchlorocarbenes to diethyl maleate, accompanied by isomerization of maleate to fumarate, is consistent with an intermediate carbene—alkene dipolar adduct.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7140c1ff08046784c131fd0be02b70fa
https://doi.org/10.1002/chin.198707154
https://doi.org/10.1002/chin.198707154