Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Michael T. Blanda"'
Publikováno v:
Journal of Physical Organic Chemistry. 22:1212-1224
The cone and 1,2,3 alternate isomers of calix[6]arene bis-crown-4 were investigated computationally. Structural optimizations, energies, bond distances, and Mulliken charges were calculated by the application of the B3LYP/6-31g(d) method/basis, follo
Publikováno v:
Tetrahedron Letters. 47:7081-7084
An inherently chiral calix[6]arene possessing a C 2 -symmetric A–B–H substitution pattern was synthesized via a two step process starting from the parent hexa- t -butylcalix[6]arene. The racemic, inherently chiral compound exists as a single isom
Publikováno v:
Polymers for Advanced Technologies. 16:146-149
Ring-opening metathesis polymerization (ROMP) of bicyclo[2,2,1]hept-2-ene (norbornene) has been effected in supercritical carbon dioxide (SC CO2) with two types of metal carbene catalysts. It has been found that the polynorbornenes prepared in SC CO2
Publikováno v:
Journal of Supramolecular Chemistry. 1:139-145
A previously known imidazole-initiated intramolecular ester migration was modified by replacing the imidazole with Cs2CO3 to effect the efficient conversion of 25, 27-bis-p-methoxy-, 25,27-bis-p-fluoro and 25, 27-bisbenzoyloxycalix[4]arene in the fla
Screening Metal Binding Selectivities of Macrocycle Mixtures by HPLC−ESI-MS and Postcolumn Reactions
Autor:
Jennifer S. Brodbelt, Dustin B. Farmer, Richard A. Bartsch, Michael T. Blanda, Esther C. Kempen
Publikováno v:
Analytical Chemistry. 73:384-390
A rapid method for the screening of metal binding selectivities of host compounds in mixtures is presented. This method involves the separation of mixtures of hosts by HPLC, followed by postcolumn complexation with one or more metals, then analysis b
Publikováno v:
Journal of the American Chemical Society. 122:1486-1491
Cone and 1,2,3-alternate stereochemical isomers of 37,40-diallyloxy-(38,42),(39,41)-bis-crown-4 calix[6]arene, 3 and 4 were isolated in moderate yields by bridging the dialkylated calix[6]arene 2 with triethylene glycol di-p-tosylate. The alkali meta
Autor:
Michael J. Rubal, Michael T. Blanda, Brian M. Osman, Patrick E. Cassidy, Rodney L. Welsch, John W. Green, John W. Fitch
Publikováno v:
Polymers for Advanced Technologies. 11:820-825
Publikováno v:
Supramolecular Chemistry. 9:255-261
Calix[4]arene molecules containing two and four silicon atoms appended to the upper rim of the cone conformation were synthesized via hydrosilation of the corresponding di- and tetra-p-allyl calixarene ethers. The p-allyl calixarene ethers were prepa
Autor:
Michael T. Blanda, Eba Adou
Publikováno v:
Polymer. 39:3821-3826
Three new copolymers containing pendant calix[4]arene units have been synthesized via radical initiated reactions involving a vinylic calix[4]arene monomer with methylacrylate, acrylonitrile, and styrene. The calix[4]arene monomer was locked into tie
Autor:
Michael T. Blanda, Michael A. Herren
Publikováno v:
ChemInform. 31
The Lewis acidic calix[4]arene with four covalently attached diphenylmonochlorotin(IV) centers was synthesized and its stannate complex with chloride was studied by 119Sn NMR.