Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Michael Tüchler"'
Autor:
Michael Tüchler, Melanie Ramböck, Simon Glanzer, Klaus Zangger, Ferdinand Belaj, Nadia C. Mösch-Zanetti
Publikováno v:
Inorganics, Vol 7, Iss 2, p 24 (2019)
Scorpionate ligands with three soft sulfur donor sites have become very important in coordination chemistry. Despite its ability to form highly electrophilic species, electron-deficient thiopyridazines have rarely been used, whereas the chemistry of
Externí odkaz:
https://doaj.org/article/f6513a66852347428f86fd0d0abaf101
Autor:
Ferdinand Belaj, Susanne Fischer, A. Daniel Boese, Lisa Gärtner, Nadia C. Mösch-Zanetti, Michael Tüchler
Publikováno v:
Angewandte Chemie International Edition. 57:6906-6909
The terminal zinc hydride complex [Tntm]ZnH (2; Tntm=tris(6-tert-butyl-3-thiopyridazinyl)methanide) is an efficient hydrosilylation catalyst of CO2 at room temperature without the need of Lewis acidic additives. The inherent electrophilicity of the s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5edea785d57abe93e6350f608ae3ec26
https://doi.org/10.1002/anie.201801800
https://doi.org/10.1002/anie.201801800
Autor:
Nadia C. Mösch-Zanetti, Luis F. Veiros, Stefan Holler, Michael Tüchler, Karl Kirchner, Ferdinand Belaj, Michaela C. Roschger
Publikováno v:
Inorganic Chemistry. 56:12670-12673
A novel selenium-containing pyridazinyl-based soft scorpionate ligand (KTnse) was synthesized. It reacts with CoCl2 and NiCl2, yielding the first metallaboratrane complexes with selenium in their donor positions. Further substitution with Ag(OTf) or
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::127a6358f59b73f38f192b950866ff6e
https://doi.org/10.1021/acs.inorgchem.7b01730
https://doi.org/10.1021/acs.inorgchem.7b01730
Autor:
Stefan Holler, Ferdinand Belaj, Susanne Fischer, Michael Tüchler, Elke Huber, Nadia C. Mösch-Zanetti, A. Daniel Boese
Publikováno v:
Organometallics. 36:3790-3798
The ligand tris(6-tert-butyl-3-thiopyridazinyl)methane ([Tntm]H) was synthesized by the reaction of 6-tert-butyl-3-thiopyridazine with bromoform and reacted with zinc bis(trimethylsilylamide) (Zn(N{SiMe3}2)2) to form [Tntm]Zn(N{SiMe3}2) (1). This com
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::50f20d6766379f5b94aca7359a7d8dae
https://doi.org/10.1021/acs.organomet.7b00568
https://doi.org/10.1021/acs.organomet.7b00568
Publikováno v:
Polyhedron. 125:122-129
The thiopyridazine based scorpionate ligand sodium tris(3,5-di-tert-butyl-6-thioxopyridazin-1(6H)-yl)hydroborate (NaTntBu,tBu) with two tert-butyl substituents in ortho- and para-position of the thio group was synthesized and fully characterized. Cor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8a22111333cac618af285fb4f72d1247
https://doi.org/10.1016/j.poly.2016.10.021
https://doi.org/10.1016/j.poly.2016.10.021
Autor:
Ferdinand Belaj, Simon Glanzer, Nadia C. Mösch-Zanetti, Klaus Zangger, Michael Tüchler, Melanie Ramböck
Publikováno v:
Inorganics, Vol 7, Iss 2, p 24 (2019)
Inorganics
Volume 7
Issue 2
Inorganics
Volume 7
Issue 2
Scorpionate ligands with three soft sulfur donor sites have become very important in coordination chemistry. Despite its ability to form highly electrophilic species, electron-deficient thiopyridazines have rarely been used, whereas the chemistry of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a5f2f0eaa3b88be0068771331af6f2ee
https://www.mdpi.com/2304-6740/7/2/24
https://www.mdpi.com/2304-6740/7/2/24
Autor:
Sarah Rendl, Natascha Stock, Michael Tüchler, Stefan Holler, Nadia C. Mösch-Zanetti, Ferdinand Belaj
Publikováno v:
European Journal of Inorganic Chemistry. 2016:2609-2614
Zinc complexes with the mixed scorpionate ligand (6-tert-butyl-3-thiopyridazinyl)bis(2-thiomethimidazolyl)borate (PnBm) have been synthesized and characterized by NMR and IR spectroscopy. The complexes, with the general formula [(PnBm)ZnX]2 [X = Br (
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0f007fcaa452ea8d913f6100bec58566
https://doi.org/10.1002/ejic.201501366
https://doi.org/10.1002/ejic.201501366
Autor:
Luis F. Veiros, Stefan Holler, Ferdinand Belaj, Karl Kirchner, Beate Gabriele Steller, Nadia C. Mösch-Zanetti, Michael Tüchler
Publikováno v:
Inorganic chemistry. 57(12)
Palladium and platinum boratrane complexes of the type [M{B(PnMe,tBu)3}(PPh3)] (M = Pd 1, Pt 2b) have been prepared via the reaction of the soft scorpionate ligand potassium tris(4-methyl-6-tert-bu...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc3454d2bdccb7eca5047df8e9e6cc31
https://pubmed.ncbi.nlm.nih.gov/29877076
https://pubmed.ncbi.nlm.nih.gov/29877076
Autor:
Michael, Tüchler, Lisa, Gärtner, Susanne, Fischer, A Daniel, Boese, Ferdinand, Belaj, Nadia C, Mösch-Zanetti
Publikováno v:
Angewandte Chemie (International ed. in English). 57(23)
The terminal zinc hydride complex [Tntm]ZnH (2; Tntm=tris(6-tert-butyl-3-thiopyridazinyl)methanide) is an efficient hydrosilylation catalyst of CO
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::bd634c8c5148c6e396e4d8b15cca080b
https://pubmed.ncbi.nlm.nih.gov/29660799
https://pubmed.ncbi.nlm.nih.gov/29660799
Publikováno v:
Inorganic Chemistry. 54:8168-8170
The soft scorpionate ligand hydrotris(6-tert-butyl-3-thiopyridazinyl)borate (Tn) was found to exhibit pronounced photoreactivity. Full elucidation of this process revealed the formation of 6-tert-butylpyridazine-3-thione (PnH) and 4,5-dihydro-6-tert-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f311f30532cd92ac3f567a4b704e30f
https://doi.org/10.1021/acs.inorgchem.5b01417
https://doi.org/10.1021/acs.inorgchem.5b01417