Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Michael L. Szalai"'
Publikováno v:
Organic Letters. 12:4944-4947
The convergent synthesis of geometrically degradable dendrimers based on the 2,4-bis(hydroxymethyl)phenol subunit is presented. The key step of the synthetic scheme involves the CuI/3,4,7,8-tetramethyl-1,10-phenanthroline-catalyzed coupling of aryl i
Publikováno v:
Macromolecules. 40:818-823
Thermally labile dendrimers based on the reversible furan−maleimide Diels−Alder reaction are described. First through fourth generation benzyl aryl ether based dendrons 3a−d that contained furan moieties at their focal point were allowed to rea
Autor:
Dominic V. McGrath, Michael L. Szalai
Publikováno v:
Tetrahedron. 60:7261-7266
Dendrimers capable of phototriggered disassembly were prepared up to the second-generation using an improved synthesis of 2,4-bis(hydroxymethyl)phenol based dendrimers. It was found that disassembly proceeds to 75–80% completion after 2 h of irradi
Publikováno v:
Journal of the American Chemical Society. 125(51)
Geometric disassembly of dendritic structures was realized by a cascade cleavage reaction triggered by an initially stimulated group at the dendrimer core. Release of an exponential number of dendrimer fragments was a result of the branching nature o
Publikováno v:
Journal of the American Chemical Society. 125:10516-10517
The disassembly of dendritic structures was realized by a cascade cleavage reaction triggered by an initially stimulated group in the dendrimer periphery. A depolymerizable backbone was engineered into prototypical dendritic structures. Evidence for
Publikováno v:
Organic Letters; Nov2010, Vol. 12 Issue 21, p4944-4947, 4p
Publikováno v:
Macromolecules; Feb2007, Vol. 40 Issue 4, p818-823, 6p