Crystal structures of metallocene complexes with uranium–germanium bonds

Autor: Michael L. Tarlton, Steven P. Kelley, Justin R. Walensky

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 12, Pp 1258-1262 (2021)

The first structural examples of complexes with uranium–germanium bonds are presented, namely, bis[3,5-bis(trifluoromethyl)phenyl-2κC1](hydrido-2κH)(iodido-1κI)bis[1,1(η5)-pentamethylcyclopentadienyl]germaniumuranium(Ge—U), [GeU(C10H15)2(C8H3

Externí odkaz: https://doaj.org/article/e1983c81fd5949089170e66c1e06066c

Crystal structures of metallocene complexes with uranium–germanium bonds

Autor: Steven P. Kelley, Michael L. Tarlton, Justin R. Walensky

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 12, Pp 1258-1262 (2021)

The first structural examples of complexes with uranium–germanium bonds are presented. The two complexes both have a long U—Ge bond [distances of 3.0428 (7) and 3.0523 (7) Å.
The first structural examples of complexes with uranium–germani

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::efcb3f3f43cae7cb242704355dc4c558
http://europepmc.org/articles/PMC8647732

Hexanitrato complexes and hybrid double perovskites of Am3+ and Cm3+

Autor: Michael L. Tarlton, Suntharalingam Skanthakumar, Valérie Vallet, Richard E. Wilson

Publikováno v: Chemical Communications
Chemical Communications, 2022, 58 (85), pp.11997-12000. ⟨10.1039/D2CC05162A⟩

International audience; The synthesis and structures of the homoleptic hexanitrato complexes of Am(III) and Cm(III), [(CH3)4N]2KAn(NO3)6 are reported. These compounds form a double perovskite structure type, A2B′BX6, crystallizing in the cubic spac

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::25747f67b5bee211dc65bdbfab583801
http://hdl.handle.net/20.500.12210/80407

Formation and Reactivity with tBuCN of a Thorium Phosphinidiide through a Combined Experimental and Computational Analysis

Autor: Michael L. Tarlton, Yan Yang, Steven P. Kelley, Justin R. Walensky, Laurent Maron

Publikováno v: Organometallics
Organometallics, 2021, 40 (15), pp.2701-2708. ⟨10.1021/acs.organomet.1c00330⟩

International audience; An investigation of the formation of a thorium phosphinidiide reveals that changing from a 2,4,6-(Pr3C6H2)-Pr-i (Tipp)-substituted phosphido ligand to a 2,4,6-Me3C6H2 (Mes) ligand forms a similar product, [(C5Me5)(2)Th](2)(P-2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23345ec7f53847d800731a82a1216274
https://doi.org/10.1021/acs.organomet.1c00330

Two-Electron Reduction of a U(VI) Complex with Al(C5Me5)

Autor: Michael L. Tarlton, Iker del Rosal, Danielle N. Chirdon, Justin R. Walensky, Steven P. Kelley, Robert J. Ward, Laurent Maron

Publikováno v: Inorganic Chemistry. 59:16137-16142

The reduction of U(VI) to U(IV) is rare, especially in one step, and not observed electrochemically as a one-wave, two-electron couple. Here, we demonstrate that reduction of the uranium(VI) bis(imido) complex, (C5Me5)2U[═N(4-OiPrC6H4)]2, is readil

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c9a5df877e11ef93ca5d8fde587b851b
https://doi.org/10.1021/acs.inorgchem.0c03036