Zobrazeno 1 - 10
of 67
pro vyhledávání: '"Michael J. Servis"'
Publikováno v:
ACS Omega, Vol 9, Iss 46, Pp 46041-46047 (2024)
Externí odkaz:
https://doaj.org/article/54f74d8168cb4725bdb349391be94003
Publikováno v:
The Journal of Physical Chemistry Letters. 13:5081-5087
Anions play significant roles in the separation of lanthanides and actinides. The molecular-scale details of how these anions behave at aqueous interfaces are not well understood, especially at high ionic strengths. Here, we describe the interfacial
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::02023b6ff6ee4891968b261da6834676
https://doi.org/10.1021/acs.jpclett.2c00934
https://doi.org/10.1021/acs.jpclett.2c00934
Publikováno v:
Encyclopedia of Inorganic and Bioinorganic Chemistry
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a42f012bb1256316a0fcabdb09dc0f81
https://doi.org/10.1002/9781119951438.eibc2767
https://doi.org/10.1002/9781119951438.eibc2767
Autor:
G B Stephenson, Michael J. Servis
Publikováno v:
The Journal of Physical Chemistry Letters. 12:5807-5812
Organic phase structure plays an important role in solute extraction energetics and phase behavior of liquid-liquid extraction (LLE) systems. For a binary extractant (amphiphile)/solvent mixture of relevance to LLE, we find that the organic phase mes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2e21c5d440eecd8a47a0d5a32249d98c
https://doi.org/10.1021/acs.jpclett.1c01429
https://doi.org/10.1021/acs.jpclett.1c01429
Publikováno v:
The Journal of Physical Chemistry B. 125:6629-6638
Solution structure in liquid-liquid extraction affects the efficacy of separation; however, even for simplified organic phases, structural characterization and attribution of aggregation to intermolecular interactions are fundamental challenges. We i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7fc28c3c8d28acd45eafbbdb153a1f81
https://doi.org/10.1021/acs.jpcb.1c02962
https://doi.org/10.1021/acs.jpcb.1c02962
Publikováno v:
Physical Chemistry Chemical Physics. 23:8880-8890
The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine. Here, we consider a binary mixture of water and an amphiphile, N,N,N',N
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1ed22b735d1528e5cca4374ae1ca44e7
https://doi.org/10.1039/d1cp00082a
https://doi.org/10.1039/d1cp00082a
Publikováno v:
Journal of Chemical Theory and Computation. 16:4579-4587
The structural features that protrude above or below a soft matter interface are well-known to be related to interfacially mediated chemical reactivity and transport processes. It is a challenge to develop a robust algorithm for identifying these org
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9434c3d6126ffde429d597c3cab4df7f
https://doi.org/10.1021/acs.jctc.0c00260
https://doi.org/10.1021/acs.jctc.0c00260
Publikováno v:
The Journal of Physical Chemistry C. 124:10924-10934
Much is understood about electrolyte liquid/liquid interfaces, yet the relationships between ion solvation, adsorption, and the instantaneous surface have not been the topic of significant study. T...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a69d97ac279f5bd30fb5c3b5ca97afac
https://doi.org/10.1021/acs.jpcc.0c00302
https://doi.org/10.1021/acs.jpcc.0c00302
Although the self-assembly of amphiphiles is well-studied in aqueous solutions, much less is understood about the fundamental driving forces and structure property relationships in non-polar media. In recent work [Journal of Physical Chemistry B, 202
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::37d5e2cb1955e9545fbf3cafdabbf0e7
https://doi.org/10.33774/chemrxiv-2021-6zndd
https://doi.org/10.33774/chemrxiv-2021-6zndd
Autor:
Christine M. Isborn, Tim J. Zuehlsdorff, Aurora E. Clark, Sapana V. Shedge, Michael J. Servis
Publikováno v:
The Journal of Physical Chemistry A. 123:6175-6184
In the condensed phase, ions often create heterogeneous local environments around a solute, which may impart chemical reactivity or perturbations to physicochemical properties. Although the former has been the subject of some study, the latter-partic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f65480063d55364d77cb4507f53c951
https://doi.org/10.1021/acs.jpca.9b03163
https://doi.org/10.1021/acs.jpca.9b03163