Zobrazeno 1 - 10
of 68
pro vyhledávání: '"Michael J. McKelvy"'
Autor:
Deirdre Gormley, Andrew Chizmeshya, Hamdallah Bearat, Ryan Nunez, Michael J. McKelvy, Kyle D. Squires, Ray Carpenter, George Wolf
Publikováno v:
Environmental Science & Technology. 40:4802-4808
CO2 sequestration via carbonation of widely available low-cost minerals, such as olivine, can permanently dispose of CO2 in an environmentally benign and a geologically stable form. We report the results of studies of the mechanisms that limit aqueou
Publikováno v:
Journal of the American Ceramic Society. 85:742-748
Gas-phase magnesium hydroxide carbonation processes were investigated at high CO2 pressures to better understand the reaction mechanisms involved. Carbon and hydrogen elemental analysis, secondary ion mass spectrometry, ion beam analysis, X-ray diffr
Publikováno v:
Philosophical Magazine. 84:2711-2729
Environmental transmission electron microscopy has been used to probe the mechanisms that govern Mg(OH)2 dehydroxylation and rehydroxylation processes at the near-atomic level. Dehydroxylation and rehydroxylation rates for these in-situ observations
Publikováno v:
Materials Chemistry and Physics. 77:416-425
We present a density functional theory investigation of the decomposition of Mg(OH)2. Based on recent experiments indicating a lamellar dehydroxylation process we have calculated the energetics, elastic behavior and structural trends of a series of o
Publikováno v:
Chemistry of Materials. 13:921-926
Lamellar dehydroxylation mechanisms are important in understanding highly reactive nanocrystal oxide formation as well as a variety of applied lamellar hydroxide reaction processes. These mechanisms have been observed for the first time via in situ n
Publikováno v:
Journal of Solid State Chemistry. 155:326-331
The reactions of methylamine, dimethylamine, and trimethylamine with TiS2 were characterized by several techniques. Detailed studies of the intercalation of methylamine demonstrated that the reaction was of the redox-rearrangement type, where the int
Publikováno v:
Journal of Solid State Chemistry. 147:38-44
The intercalation and deintercalation of NH3 into ZrS2 has been investigated by evolved gas analysis, thermogravimetric analysis, differential scanning calorimetry, vapor pressure measurements, SQID magnetometry, and X-ray powder diffraction. Ammonia
Publikováno v:
Journal of Solid State Chemistry. 145:336-344
The intercalation and deintercalation processes for nearly stoichiometric 1T-TaS 2 have been investigated by X-ray powder diffraction, thermogravimetric analysis, differential scanning calorimetry, and mass spectrometry. The maximum ammonia stoichiom
Publikováno v:
Journal of Solid State Chemistry. 141:330-337
High-resolution transmission electron microscopy has been used to observe the host-layer restacking process in situ during Hg x TiS 2 (1.24≥ x ≥0.00) deintercalation to better understand the role of elastic strain in reaction dynamics and phase f
Publikováno v:
Chemistry of Materials. 10:3290-3293
Electron diffraction has been used to observe in situ HgxTiS2 (1.24 > x ≥ 0.00) guest-layer structural behavior as a function of temperature. At low temperature (−170 °C), Hg forms well-ordered inc...