Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Michael J. McGeary"'
Publikováno v:
ChemInform. 22
Publikováno v:
Polyhedron. 11:1369-1382
Neutral bis-silyloxidetin(II) dimers [Sn(OSiPh3)(μ-OSiPh3)]2 (1) and [Sn{OSi(tBu)Me2}{μ-OSi(tBu)Me2}] 2 (2) were synthesized in one step from [Sm{N(SiMe3)2}2] and 2 equiv. of silanol. Complexes 1 and 2 were characterized by IR, NMR (1H, 13C and 119
Publikováno v:
Polyhedron. 11:2459-2473
Homoleptic copper(I) silyloxide complexes [Cu(OSiR 3 )] 4 [SiR 3 = SiPh 3 ( 2 ), SiPh 3 ·toluene ( 1 ) SiMe 2 Bu t ( 3 ), SiEt 3 ( 4 )] were prepared by reaction of copper(I) mesityl with equivalent amounts of silanol. Reaction of [Cu(OSiR 3 )] 4 wi
Publikováno v:
Inorganic Chemistry. 30:1723-1735
Reaction of (M(N(SiMe{sub 3}){sub 2}){sub 3}) (M = Y, La) with 3 equiv of Ph{sub 3}SiOH in toluene gave high yields of (M(Oiph{sub 3}){sub 3}){sub n}. The homoleptic tris-((triphenylsilyl)oxy)yttrium and -lanthanum complexes could be converted nearly
Publikováno v:
Polyhedron. 10:2699-2709
Lithium and potassium silyloxide complexes [Li(OSiPh3)]n (1), [K(thf)0.2 (OSiPh3)]n (3) and [K(OSiMe2tBu)]n (6) were prepared by deprotonation of HOSiPh3 or HOSiMe2tBu with [Li(nBu)] in hexane or KH in THF, respectively. Crystalline DME adducts [Li(
Publikováno v:
Inorganic Chemistry. 30:3570-3572
The authors reported that treatment of Y(N(SiMe{sub 3}){sub 2}){sub 3} with Ph{sub 3}SiOH in toluene gives a high yield of a material of empirical formula Y(OSiPH{sub 3}){sub 3}. On the basis of its low solubility and its complex {sup 1}H and {sup 13
Publikováno v:
Journal of the American Chemical Society. 112:5658-5660
Publikováno v:
Organometallics. 9:884-886
The crystalline complex [{Fe(CO) 3 (μ-CO)}-(SnFp 2 )]-(O-Sn) (1), [{Cr(CO) 4 (μ-CO)}(SnFp 2 )] 2 -(O,Sn) (2), and [Fe(CO) 4 {SnFp 2 (Py)}] (3) [Fp=Fe(η-C 5 H 5 )(CO) 2 ] have been prepared; X-ray data on 1 and 2 show them to be centrosymmetric dim
Publikováno v:
ChemInform. 21
Publikováno v:
Organometallics. 9:2645-2646
The crystalline, blue, diamagnetic complex [(W(η 2 -S 2 CNEt 2 )) 2 (μ-CNEt 2 )(μ-S)(μ-S 2 CNEt 2 )(μ-S 2 SnR 2 )]-(W,W) (3) was obtained by heating [W(CO) 2 (η 2 -S 2 CNEt 2 ) 2 (SnR 2 )] (R=CH(SiMe 3 ) 2 ) under reflux in benzene: single-crys