Structural characterization of some adducts of the form [M2(μ-dppm)2(MeCN)x]X2 [M = Cu, Ag; X = ClO4, BF4, PF6; dppm = (Ph2P)2CH2; x = 0–4]

Autor: Allan H. White, Brian W. Skelton, Natasha N. Zaitseva, Michael I. Bruce, Brian K. Nicholson

Publikováno v: Inorganica Chimica Acta. 453:647-653

Structural characterizations are reported for a number of adducts of the form [M2(μ-dppm)2(MeCN)x]X2 (M = univalent Cu, Ag; X = ClO4, BF4, PF6; dppm = Ph2PCH2 PPh2; x = 0–4) for (a) M = Cu, X = BF4, x = 4 (1), 3 (2); (b) M = Ag, x = 2, X = BF4 (3)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6c95b3d30541f12f3d4e26724a009a17
https://doi.org/10.1016/j.ica.2016.09.018

Structural systematics of some trinuclear alkynyl and diynyl Group 11 complexes containing dppm [dppm = CH 2 (PPh 2 ) 2 ]

Autor: Jean François Halet, Allan H. White, Brian W. Skelton, Christopher J. Sumby, Alexandre N. Sobolev, Boris Le Guennic, Michael I. Bruce

Publikováno v: Coordination Chemistry Reviews
Coordination Chemistry Reviews, Elsevier, 2018, 375, pp.2-12. ⟨10.1016/j.ccr.2017.09.021⟩
Coordination Chemistry Reviews, Elsevier, In press, 〈10.1016/j.ccr.2017.09.021〉
Coordination Chemistry Reviews, 2018, 375, pp.2-12. ⟨10.1016/j.ccr.2017.09.021⟩

International audience; In this review the molecular structures of a series of trinuclear alkynyl and diynyl Group 11 cations [{M3(μ-dppm)3}(X)n](3−n)+ (M = Cu, Ag; n = 1, 2; where X is an alkynyl or diynyl group, an inorganic anion or solvent) ar

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cf16ddd3b8be2409403c4fdb321b93a
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01812447

The series of carbon-chain complexes {Ru(dppe)Cp∗}2{μ-(C C) } (x= 4–8, 11): Synthesis, structures, properties and some reactions

Autor: Christian R. Parker, Maryka Gaudio, Brian W. Skelton, Allan H. White, Brian K. Nicholson, Benjamin G. Ellis, Marcus L. Cole, Michael I. Bruce

Publikováno v: Polyhedron. 86:43-56

The construction of a series of compounds {Ru(dppe)Cp∗}2(μ-C2x) (Ru∗-C2x-Ru∗, x = 4–8, 11)) is described. A direct reaction between RuCl(dppe)Cp∗ and Me3Si(C C)4SiMe3 afforded Ru∗-C8-Ru∗ in 89% yield. The Pd(0)/Cu(I)-catalysed coupling

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c626321a3aa22c40c63f3c07e671a52b
https://doi.org/10.1016/j.poly.2014.04.052

Syntheses and Structural Studies of Several Group 8 Metal Complexes Derived from 1, 3-Butadiyne

Autor: Brian W. Skelton, Gary J. Perkins, Benjamin G. Ellis, Claude Lapinte, Marcus L. Cole, Michael I. Bruce, Natasha N. Zaitseva, Kathy A. Kramarczuk, Allan H. White, Brian K. Nicholson, Karine Costuas

Publikováno v: Zeitschrift für anorganische und allgemeine Chemie. 639:2216-2223

As part of an extensive investigation into the chemistry of complexes containing metal-ligand centers linked by chains of C(sp) atoms, the preparation, characterization, and single-crystal X-ray diffraction molecular structure determinations of four

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8d095ff0d665d86ac52b09a4c0ee7f48
https://doi.org/10.1002/zaac.201300282

Oxidative Activation of Aryldiynyl–Iron Complexes: Regioselective Dimerization

Autor: Michael I. Bruce, Sourisak Sinbandhit, Jean-François Halet, Claude Lapinte, Thierry Roisnel, Frédéric Gendron, Karine Costuas, Alexandre Burgun

Publikováno v: Organometallics
Organometallics, 2013, 32 (6), pp.1866−1875. ⟨10.1021/om400014g⟩
Organometallics, American Chemical Society, 2013, 32 (6), pp.1866−1875. ⟨10.1021/om400014g⟩

International audience; Chemical oxidations of the iron butadiynyl complexes Cp*(dppe)FeC≡CC≡CAr (Ar = Ph, 1a; Ar = C6H4-Me-4, 1b; Cp* = η5-C5Me5, dppe = 1,2-bis(diphenylphosphino)ethane) achieved with 1 equiv of ferrocenium hexafluorophosphate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8383d85db3148f898369e9024518d71d
https://doi.org/10.1021/om400014g