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pro vyhledávání: '"Michael Histed"'
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :267
An electron paramagnetic resonance spectroscopic study of the reaction of ground-state Al atoms with acetylene in cyclohexane and adamantane at 77 K has demonstrated that transη1-aluminovinyl, AICHCH is the initial paramagnetic product and that it d
Publikováno v:
Faraday Discussions. 92:129
Small paramagnetic metal cluster, Mn(n < 13) of Group 1, 3, 11 and 13 elements have been prepared by the matrix-isolation technique and their geometric and electronic structures determined by EPR.The trimeric clusters of the alkali metals have either
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 84:3307
Al atoms react with propenes and butenes in a rotating cryostat at 77 K to give a range of organoaluminium products including aluminium monoalkene complexes, π-allyl aluminium hydrides and aluminacyclopentanes, but no β-aluminoalkyls. In addition a