Zobrazeno 1 - 10
of 48
pro vyhledávání: '"Michael E. Sitzmann"'
Autor:
John W. Fronabarger, Michael E. Sitzmann, Magdy Bichay, William B. Sanborn, Ray J. Butcher, Richard Gilardi, Michael D. Williams
Publikováno v:
Tetrahedron Letters. 47:6663-6666
Guanazine (3,4,5-triamino-1,2,4-triazole) is selectively nitrosated on C–NH 2 to produce nitrosoguanazine (3-nitrosamino-4,5-diamino-1,2,4-triazole). The nitrosoguanazine is used to prepare 5-azido-3-amino-1,2,4-triazole and nitrosoguanazine anion
Autor:
Michael E. Sitzmann, Jean'ne M. Shreeve, Rolf W. Winter, Chengfeng Ye, Haixiang Gao, Gary L. Gard
Publikováno v:
European Journal of Inorganic Chemistry. 2006:3221-3226
New quaternary salts of pentafluorosulfanyl-substituted (SF5) N-methylimidazole (1), 4-amino-1,2,4-triazole (3) or pyridine (5) were prepared and characterized. Most of the salts exhibit good thermal stabilities and low melting points placing them in
Autor:
Michael E. Sitzmann, Patrick B. Skahan, Alfred G. Stern, Lori A. Nock, James A. Kenar, Nirupam J. Trivedi
Publikováno v:
Propellants, Explosives, Pyrotechnics. 31:124-130
A process for N-butyl-N-(2-nitroxyethyl)nitramine (BuNENA) was investigated: Step 1 involves N-butyl-ethanolamine addition to 98% HNO3 to form a salt mixture; Step 2 is addition of acetic anhydride/acetyl chloride catalyst to the salt mixture. A numb
Autor:
Michael E. Sitzmann, Michael D. Williams, William B. Sanborn, John W. Fronabarger, Richard Gilardi, Magdy Bichay
Publikováno v:
Journal of Heterocyclic Chemistry. 42:1117-1125
The synthesis and properties of hydroxynitrobenzodifuroxan (5-nitro[1,2,5]oxadiazolo[3,4-e][2,1,3]ben-zoxadiazol-4-ol-3,8-dioxide) (1) and its salts (four metal and three amine salts) are described. Crystal structure analyses indicate that the hydrox
Autor:
Michael E. Sitzmann
Publikováno v:
Journal of Fluorine Chemistry. 70:31-38
1,3,4-Oxadiazoles containing a combination of SF 5 -perfluoroalkyl, SF 5 -alkyl, polynitroalkyl and perfluoroalkyl substituents have been synthesized by cyclization (dehydration) of the corresponding diacyl hydrazines. The properties of oxadiazoles w
Autor:
Michael E. Sitzmann
Publikováno v:
Propellants, Explosives, Pyrotechnics. 19:249-254
The preparation and properties of high-melting aromatic nitrate esters are described. An objective of the study is to provide nitrate esters that exhibit good short-term stability at temperatures of 150°C and above.
Autor:
Michael E. Sitzmann, R.D. Gilardi
Publikováno v:
Journal of Fluorine Chemistry. 63:203-215
Polynitroalkyl SF5 imines have been synthesized from SF5NCCl2 via nucleophilic substitution and nitration reactions. Only in one instance was the SF5 imino moiety (SF5NC) affected by a nitration reagent; the product was the fluorosulfonyl co
Autor:
Michael E. Sitzmann, Horst G. Adolph
Publikováno v:
ChemInform. 22
An improved synthesis of 2,2,2-trinitroethyl ethers (from iodomethyl ethers and trinitromethane) that avoids the use of unstable potassium trinitromethide is described.
Autor:
Michael E. Sitzmann
Publikováno v:
ChemInform. 23
Unlike N-alkyl carbamates, N-pentafluorosulfanyl carbamates (SF 5 NHCO 2 R) did not readily undergo nitration to provide the N-NO 2 derivatives. Although trifluoroacetyl nitrate did provide nitration, work-up yielded a mixture of SF 5 N(NO 2 )CO 2 R
Autor:
Michael E. Sitzmann
Publikováno v:
ChemInform. 26
1,3,4-Oxadiazoles containing a combination of SF 5 -perfluoroalkyl, SF 5 -alkyl, polynitroalkyl and perfluoroalkyl substituents have been synthesized by cyclization (dehydration) of the corresponding diacyl hydrazines. The properties of oxadiazoles w