Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Michael E. Limmert"'
Publikováno v:
The Journal of Organic Chemistry. 70:9364-9370
[Reaction: see text]. Aryl and alkenyl tosylates are easily prepared, inexpensive and, thus, attractive for transition-metal-catalyzed couplings, but their reactivity is low. We report examples of mild, palladium-catalyzed coupling of aryl, alkenyl,
Autor:
Michael E. Limmert, Robin B. Bedford
Publikováno v:
The Journal of Organic Chemistry. 68:8669-8682
The use of rhodium catalysts such as [RhCl(PPh3)3] or [{RhCl(COD)}2] with PiPr2(OAr) or P(NMe2)3 co-catalysts allows the ortho-selective intermolecular arylation of phenols. The reaction proceeds via orthometalation of P-OAr groups and then transeste
Autor:
Michael E. Limmert, David A. Albisson, Michael B. Hursthouse, Simon J. Coles, Samantha L. Hazelwood, P. Noelle Scully, Robin B. Bedford, Sylvia M. Draper
Publikováno v:
Chemistry - A European Journal. 9:3216-3227
Bulky triarylphosphite ligands undergo facile orthometallation reactions with palladium and platinum precursors. The crystal structure of an example of the resultant palladacycles has been determined. The reactivity of some of the metallacycles with
Autor:
Robin B. Bedford, Simon J. Coles, Andrew R. Cowley, John M. Brown, Michael E. Limmert, Shailesh Ramdeehul, Michael B. Hursthouse, Samantha L. Hazelwood
Publikováno v:
Organometallics. 22:1364-1371
The orthometalated complex [{Pd(μ-Cl){κ2-P,C-P(OC6H2-2,4-tBu2)(OC6H3-2,4-tBu2)2}}2] reacts with phenylboronic acid hydrate and K2CO3 in dimethylacetamide to give [Pd{κ2-P,C-μ2-O-P(O)(C6H2-2,4-tBu2)(C6H3-2,4-tBu2)(DMAc)}]. When the reaction is rep
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 629:223-231
Nach Uberfuhrung des Fluorophors N-Benz[cd]indol-2(1H)-on (= Naphtholactam) mit NaN(SiMe3)2 in das Naphtholactamat 1 und Umsetzung mit den Chlorokomplexen [Ph3PAuCl] und [(Ph3P)2PtCl2] entstehen die Mono- bzw. Disubstitutionsprodukte [Ph3PAu(C11H6NO)
Publikováno v:
Angewandte Chemie (International ed. in English). 42(1)
Autor:
Holger Piotrowski, Kurt Polborn, Heinz Langhals, Peter Mayer, Martin Poppe, Ingo-Peter Lorenz, Michael E. Limmert
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 8(17)
The DPP dyes (=diketopyrrolopyrrole) 1 are deprotonated to give the corresponding dianions 2. These are treated with two moles of the transition-metal complexes [L(n)MX]=[(Ph(3)P)(2)MX] (M=Cu, Ag; X=Cl, NO(3)), [(Ph(3)P)AuCl], [(Et(3)P)AuCl], [(tBuNC
Autor:
Robin B. Bedford, Samantha L. Hazelwood (néeWelch), Michael E. Limmert, David A. Albisson, Sylvia M. Draper, P. Noelle Scully, Simon J. Coles, Michael B. Hursthouse
Publikováno v:
Chemistry - A European Journal; Jul2003, Vol. 9 Issue 14, p3216-3227, 12p