Zobrazeno 1 - 10
of 260
pro vyhledávání: '"Michael D. Fryzuk"'
Publikováno v:
Dalton Transactions. 50:17140-17149
The synthesis and reactivity of the bimetallic rhodium–copper complex, Rh(COE)[P2N2]Cu, which is stabilized by the P2N2 macrocycle, is reported. In the solid state, the rhodium and copper centers are on opposite sides of the macrocyclic ring with t
Publikováno v:
Dalton Transactions. 50:899-907
The reaction of the dilithium diamido-diphosphine macrocycle, Li2[N(SiMe2CH2P(Ph)CH2SiMe2)2N] (Li2[P2N2]) with [Rh(COD)Cl]2 generates the dirhodium macrocyclic compound, [P2N2][Rh(COD)]2 (where COD = η4-1,5-cyclooctadiene), wherein both rhodium-COD
Publikováno v:
European Journal of Inorganic Chemistry. 2020:1465-1471
Autor:
Michael D. Fryzuk, Amanda C. Zimmerman
Publikováno v:
Organometallics. 38:3671-3679
The nickel(II) complex [κ3-BnPPC]NiBr (1), stabilized by an orthometalated-phosphine benzyl group and two bulky phosphine donors, results in facile reductive elimination with certain organometallic...
Autor:
Amanda C. Zimmerman, Michael D. Fryzuk
Publikováno v:
Organometallics. 37:2305-2318
The incorporation of a PPC donor ligand set onto nickel is described. While C–H activation routes using Ni(II) precursors and benzyl- and phenethyl-substituted diphosphines But2PCH2CH2P(But)R failed, success was achieved via oxidative addition of t
Autor:
Tomohiko Inomata, Tomohiro Ozawa, Hideki Masuda, Keisuke Fujimoto, Michael D. Fryzuk, Yoshiyuki Takemoto, Tatsuya Suzuki, Yuko Wasada-Tsutsui
Publikováno v:
ACS Catalysis. 8:3011-3015
Incorporation of the tridentate phosphine-enamidoiminophosphorane onto cobalt(II) produces tetrahedral Co(NpNPiPr)Cl, 1, which upon reduction under dinitrogen generates the T-shaped, paramagnetic Co(I) complex Co(NpNPiPr), 2. This paramagnetic T-shap
Publikováno v:
Dalton Transactions. 47:10925-10931
The redox behaviour of the dimeric tetrairon complex, ([fc(NPiPr2)2]Fe)2 (where fc(NPiPr2)2 = 1,1'-(C5H4NPiPr2)2Fe) has been investigated. Upon reduction with KC8 an Fe-Fe bond is formed with the complex maintaining a high spin configuration and havi
Publikováno v:
Organometallics. 36:3564-3572
The thermolysis of [PhP(CH2SiMe2NPh)2]TaMe3 leads to the elimination of methane and the formation of cyclometalated derivative [PhP(CH2SiMe2NPh)(CH2SiMe2N-o-C6H4)]TaMe2, which was characterized by NMR spectroscopy and single crystal X-ray analysis. C
Publikováno v:
Coordination Chemistry Reviews. 334:84-99
This review surveys the iterative approaches to ligand design for groups 4 and 5 transition metal complexes relevant to nitrogen fixation made by the Fryzuk group over the last 25 years. The coordination chemistry of multidentate ligands that incorpo
Autor:
Vincent T. Annibale, Stefan Westhues, Michael D. Fryzuk, Truman C. Wambach, Thomas G. Ostapowicz
Publikováno v:
Dalton Transactions. 45:16011-16025
In order to generate tridentate enamido diphosphine ligand platforms, we developed procedures for the preparation of tBu2PCH2CH2P(tBu)I, which involve low temperatures, pentane solvent and addition of 4 equiv. of tBuLi to Cl2PCH2CH2PCl2 or 2 equiv. o