Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Michael D. Clift"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 2895-2901 (2017)
A new method for imine synthesis by way of quinone-catalyzed oxidative deformylation of 1,2-amino alcohols is reported. A wide range of readily accessible amino alcohols and primary amines can be reacted to provide N-protected imine products. The met
Externí odkaz:
https://doaj.org/article/481607032a1e481abbf6a8cf2e91b109
Publikováno v:
Organic Letters. 23:7008-7013
New methods for C-N bond construction exploiting the N-centered electrophilic character of iminoquinones are reported. Iminoquinones, generated in situ via the condensation of o-vinylanilines with benzoquinones, undergo acid-catalyzed cyclization to
Publikováno v:
The Journal of Organic Chemistry. 85:14827-14846
N-(Aryloxy)imines, readily accessible by condensation/tautomerization of (pseudo)benzylic primary amines and 2,6-di-tert-butyl-1,4-benzoquinone, undergo efficient allylation to afford a wide range of homoallylic primary amines following hydrolytic wo
Publikováno v:
The Journal of organic chemistry. 85(23)
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 2895-2901 (2017)
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry
A new method for imine synthesis by way of quinone-catalyzed oxidative deformylation of 1,2-amino alcohols is reported. A wide range of readily accessible amino alcohols and primary amines can be reacted to provide N-protected imine products. The met
Total syntheses of the antibacterial alkaloids berberine, coptisine, and jatrorrhizine have been achieved in four steps through a unified route. The key step of this strategy is an efficient intramolecular Friedel–Crafts alkoxyalkylation which, fol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::27fce645ee20648b5d2ca00dae84821d
https://europepmc.org/articles/PMC6426129/
https://europepmc.org/articles/PMC6426129/
Publikováno v:
The Journal of organic chemistry. 83(11)
Publikováno v:
The Journal of organic chemistry. 82(23)
The pentacyclic alkaloid calothrixin B (1) has been synthesized in 5 steps from murrayaquinone A (9). The key step involved the union of boryl aniline 31 with brominated murrayaquinone A (26). In this transformation, alkylquinone 26 undergoes tautome
Publikováno v:
Chemical communications (Cambridge, England). 53(21)
A new method for amino acid homologation by way of formal C–C bond functionalization is reported. This method utilizes a 2-step/1-pot protocol to convert α-amino acids to their corresponding N-protected β-amino esters through quinone-catalyzed ox
Publikováno v:
Journal of the American Chemical Society
Direct β-alkylation of saturated aldehydes has been accomplished by synergistically combining photoredox catalysis and organocatalysis. Photon-induced enamine oxidation provides an activated β-enaminyl radical intermediate, which readily combines w