Výsledky vyhledávání - "Michael C. Norton"

Transition metal–carbon bonds. Part 52. Large ring and cyclometallated complexes formed from But2PCH2CH2CHRCH2CH2PBut2(R  H or Me) and IrCl3, or [Ir2Cl4(cyclo-octene)4] : crystal structures of the cyclometallated hydride, [IrHCl(But2PCH2CH2CHCH2CH2PBut2)], and the carbene complex [IrCl(But2PCH2CH2CCH2CH2PBut2)]

Autor: Richard Markham, Eileen M. Hyde, Brian Weeks, H. David Empsall, Bernard L. Shaw, Christopher Crocker, R. John Errington, Walter S. McDonald, Michael C. Norton

Publikováno v: J. Chem. Soc., Dalton Trans.. :1217-1224

Treatment of But2P(CH2)5PBut2, with iridium trichloride gives a mixture of the 16-atom ring dihydride [lr2H2Cl4{But2P(CH2)5PBut2}2], a co-ordinatively saturated cyclometallated hydride, [[graphic omitted]But2)])(1b), which is non-fluxional, and an un

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3648e529cea8e1501738691008336d2a
https://doi.org/10.1039/dt9820001217

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Some unusual iridium complexes formed from (2,6-dimethoxyphenyl) and (2,3-dimethoxyphenyl)-di-t-butylphosphine: crystal structure of [2-di-t-butylphosphino-3-methoxyphenoxo-OP]{2-[(2-hydroxy-6-methoxyphenyl)t-butylphosphino]-2-methylpropanato(2—)-C1PO2}-(methyl isocyanide)iridium(III)

Autor: Peter N. Heys, H. David Empsall, Walter S. McDonald, Michael C. Norton, Bernard L. Shaw

Publikováno v: J. Chem. Soc., Dalton Trans.. :1119-1126

The compound PBut2[C6H3(OMe)2-2,6] reacts with iridium trichloride in propan-2-ol to give the purple five-co-ordinate hydride [[graphic omitted]But2-2)}2](1). This hydride in solution is converted by air into the red paramagnetic iridium(II) complex

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5e8e0ef5e7d14d2df8070c8021c3a318
https://doi.org/10.1039/dt9780001119

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Formation of large chelate rings and cyclometallated complexes from But 2PCH2CH2CHMeCH2CH2PBut 2 and platinum and palladium chlorides. Crystal structure of [Pd2Cl4{But 2PCH2CH2CHMeCH2CH2PBUt 2}2]

Autor: Bernard L. Shaw, Najeeb A. Al-Salem, Richard Markham, Michael C. Norton, Walter S. McDonald

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :59

Treatment of [PdCl2(NCPh)2] with But2 PCH2CH2CHMeCH2CH2PBut2(Q) gives the binuclear complex [Pd2Cl4(But2PCH2CH2CHMeCH2CH2PBut2)2]. The crystal structure of this 16-atom ring complex shows that the two methyl substituents on the ring occupy ‘corner

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::431253fa10e088008236d26fbe7bb65c
https://doi.org/10.1039/dt9800000059

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Synthesis and X-ray structure of an unusual iridium ylide or carbene complex

Autor: H. David Empsall, Walter S. McDonald, Bernard L. Shaw, Brian Weeks, Richard Markham, Eileen M. Hyde, Michael C. Norton

Publikováno v: Journal of the Chemical Society, Chemical Communications. :589

IrCl3 reacts with But2P[CH2]5PBut2 to give [[graphic omitted]] which loses dihydrogen reversibly to give [[graphic omitted]], the structure of which has been determined by X-ray diffraction.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e8e4fe07556d3b447dd484e2546c68f8
https://doi.org/10.1039/c39770000589

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