Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Michael B. Pushkarsky"'
Autor:
Michael E. Webber, Frank M. Mitloehner, Nichole Marcillac, Yongjing Zhao, Michael B. Pushkarsky, C. Kumar N. Patel, Tyson MacDonald
Publikováno v:
Measurement Science and Technology. 16:1547-1553
A trace-gas sensor based on fibre-amplifier enhanced photoacoustic spectroscopy has been developed for measuring ambient ammonia in agricultural settings. The sensor was built in an enclosure for continuous, unattended operation in dusty and humid co
Publikováno v:
Applied Physics B. 77:381-385
An ambient trace-ammonia sensor that uses resonant photoacoustic spectroscopy and a line-tunable CO2 laser has been developed. This system achieves a 1σ replicate precision of 32 parts-per-trillion (ppt) with an averaging time of 5 s and a total mea
Publikováno v:
The Journal of Chemical Physics. 115:10738-10744
The spectra of the X2A′-A2A″ electronic transition of jet-cooled vinyl radical, C2H3, and its partially deuterated isotopomer, CD2CH, have been obtained via action spectroscopy. The appearance of the H or D fragment was monitored via 1+1′ reson
Publikováno v:
The Journal of Chemical Physics. 113:9649-9657
The radiative and nonradiative decay of the A 2E electronic state of the CH3S radical has been investigated using a variety of experimental techniques. Lifetimes have been measured for a number of vibrational levels; these data have been analyzed alo
Publikováno v:
The Journal of Chemical Physics. 112:10695-10698
Cavity ringdown spectra of the A 2A′−X 2A″ electronic transition in the IR are reported for the methyl and ethyl peroxy radicals. Analysis of partially resolved rotational structure for the origin band of the transition provides information abo
Publikováno v:
The Journal of Chemical Physics. 110:2016-2028
The fluorescence depletion spectroscopy (FDS) technique has been applied to the A 2E electronic state of the CdCH3 radical to investigate “dark” vibronic levels. The observed FDS spectrum complements the sparse laser-induced fluorescence and reso
Publikováno v:
The Journal of Chemical Physics. 106:6863-6877
The laser induced fluoresence excitation spectrum for the A 2A1↔X 2E transition of the methoxy radical has been reinvestigated. An extensive set of vibrational levels has been assigned with the aid of increased vibrational and rotational cooling. M
Publikováno v:
Chemical Physics Letters. 247:548-554
The spectrum of the CF 3 S free radical has been observed for the first time cooled in a supersonic free jet expansion. Both ‘bright’ and ‘dark’ levels of the A state have been observed using a combination of laser-induced fluorescence and fl
Autor:
Manu Prasanna, Rowel Go, Alexei Tsekoun, Michael B. Pushkarsky, C. Kumar N. Patel, I. Dunayevskiy
Publikováno v:
Proceedings of the National Academy of Sciences of the United States of America. 103(52)
We report high-sensitivity detection of 2,4,6-trinitrotoluene (TNT) by using laser photoacoustic spectroscopy where the laser radiation is obtained from a continuous-wave room temperature high-power quantum cascade laser in an external grating cavity
Publikováno v:
Proceedings of the National Academy of Sciences of the United States of America. 103(29)
We report the sub-parts-per-billion-level detection of NO 2 using tunable laser-based photoacoustic spectroscopy where the laser radiation is obtained from a room-temperature continuous-wave high-power quantum cascade laser operating in an external g