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pro vyhledávání: '"Michael A. K. Weinhart"'
Autor:
Robert Szlosek, Michael A. K. Weinhart, Gábor Balázs, Michael Seidl, Lisa Zimmermann, Manfred Scheer
A missing family of the extremely air sensitive tripentelyltrielanes was discovered. Their stabilisation was achieved by using the bulky NHC IDipp (NHC=N-heterocyclic carbene, IDipp=1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene). The tripentely
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3cd128c0d7fe6fe3aa2d41b00adc9878
Publikováno v:
Angewandte Chemie. 133:3850-3855
Publikováno v:
Angewandte Chemie (International Ed. in English)
The synthesis and characterization of the unprecedented compounds IDipp⋅E′H2AsH2 (E′=Al, Ga; IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) are reported, the first monomeric, parent representatives of an arsanylalane and arsa
Publikováno v:
Angewandte Chemie. 132:5586-5590
The synthesis and characterization of the first parent phosphanylalane and phosphanylgallane stabilized only by a Lewis base (LB) are reported. The corresponding substituted compounds, such as IDipp.GaH2PCy2 (1) (IDipp=1,3-bis(2,6-diisopropylphenyl)-
Publikováno v:
Angewandte Chemie (International Ed. in English)
The synthesis and characterization of the first parent phosphanylalane and phosphanylgallane stabilized only by a Lewis base (LB) are reported. The corresponding substituted compounds, such as IDipp⋅GaH2PCy2 (1) (IDipp=1,3‐bis(2,6‐diisopropylph
Publikováno v:
Dalton Transactions. 49:4665-4668
A complex of an N-heterocyclic carbene ItBu (1,3-di-tert-butylimidazolin-2-ylidene) and aluminum hydride was observed to isomerize into an abnormal carbene complex aItBu·AlH3 (aItBu = 1,3-di-tert-butylimidazolin-4-ylidene) in a polar solvent, and, f
Autor:
Michael A. K. Weinhart, Matthias Tamm, Adinarayana Doddi, Alexander Hinz, Manfred Scheer, Dirk Bockfeld, Jose M. Goicoechea
Publikováno v:
Chemical communications (Cambridge, England). 53(45)
A series of novel N-heterocyclic carbene-arsinidene adducts was prepared by two different synthetic routes. Reactions of the difluoro imidazolines (IPr)F2 (1a, 1,3-bis(2,6-diisopropylphenyl)-2,2-difluoroimidazoline) and (IMes)F2 (1b, 1,3-bis(2,4,6-tr