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of 180
pro vyhledávání: '"Michael T. H. Liu"'
Publikováno v:
Molecules, Vol 25, Iss 16, p 3626 (2020)
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are dis
Externí odkaz:
https://doaj.org/article/93a4e83ae30d403a81220f206236dc8c
Publikováno v:
Molecules
Molecules, Vol 25, Iss 3626, p 3626 (2020)
Molecules, Vol 25, Iss 3626, p 3626 (2020)
This overview explains some new aspects of chemical functionalization of endohedral metallofullerenes (EMFs) that have been unveiled in recent years. After differences in chemical reactivity between EMFs and the corresponding empty fullerenes are dis
Autor:
Michael T. H. Liu, Takayoshi Kono, Takahiro Tsuchiya, Takatsugu Wakahara, Shigeru Nagase, Naomi Mizorogi, Takeshi Akasaka, Tatsuhisa Kato, Yutaka Maeda, Zdenek Slanina, Yoichiro Matsunaga, Tsukasa Nakahodo, Midori O. Ishitsuka
Publikováno v:
The Journal of Physical Chemistry A. 112:1294-1297
The photochemical reaction of La@C82(Cs) with 2-adamantane-2,3-[3H]-diazirine (1) affords the adduct 2 of La@C82(Cs) with adamantylidene (Ad:) in a high selectivity. The two isomers of La@C82(Cs)(Ad), 2a and 2b, are isolated by HPLC and characterized
Autor:
Michael T. H. Liu, Takeshi Akasaka, Takatsugu Wakahara, Midori O. Ishitsuka, Satoru Sato, Takahiro Tsuchiya, Michio Yamada
Publikováno v:
Tetrahedron Letters. 48:6290-6293
The photochemical reaction of C 60 with 3-trifluoromethyl-3-phenyldiazirine affords a photo-labeled C 60 derivative. The derivative was characterized by mass, UV–vis absorption, NMR spectroscopy, and X-ray crystallographic analysis. The redox poten
Autor:
Michael T. H. Liu, Roland Bonneau
Publikováno v:
European Journal of Organic Chemistry. 2005:1532-1540
Phenylchlorocarbene, generated by photolysis or thermolysis of the phenylchlorodiazirine, reacts with 2,2'-bipyridyl to give, in alkane solvents, the 6-phenyldipyrido[1,2-c:2',1'-e]imidazolium chloride. We investigated the mechanism of the reaction b
Autor:
Yutaka Maeda, Kaoru Kobayashi, Michael T. H. Liu, Takeshi Akasaka, Yasuyuki Niino, Takashi Kato, Takatsugu Wakahara, Shigeru Nagase
Publikováno v:
Journal of the American Chemical Society. 124:9465-9468
C(60) acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C(60) to
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 126:31-36
Laser Flash Photolysis of arylchlorodiazirines in isooctane/CH2Cl2 in the presence of substituted vinylpyridines yields substituted vinylpyridinium ylide (λ = 540 nm). As the ylide decays a concomitant growth causes an absorption at 330 nm, attribut
Autor:
Michael T. H. Liu, Yutaka Maeda, Tsukasa Nakahodo, Takahiro Tsuchiya, Shigeru Nagase, Takeshi Akasaka, Naomi Mizorogi, Yuko Iiduka, Takatsugu Wakahara, Koji Nakajima, Kenji Yoza
Publikováno v:
Angewandte Chemie International Edition. 46:5562-5564
Autor:
Hidefumi Nikawa, Haruka Enoki, Takahiro Tsuchiya, Takeshi Akasaka, Takatsugu Wakahara, Midori O. Ishitsuka, Michael T. H. Liu
Publikováno v:
Tetrahedron Letters. 48:859-861
By employing C 60 as a chemical probe, the photolysis of benzylchlorodiazirine has been proposed to form carbene and the rearranged products via the excited state.
Publikováno v:
The Journal of Physical Chemistry A. 101:2509-2513
The stereochemistry of 1,2-H migration in ethylchlorocarbene (1) and chloromethylchlorocarbene (2) has been studied by ab initio methods. Geometries of the ground and transition states of a conformational equilibrium and the 1,2 rearrangement were op