Exploiting Interactions between Polyoxometalates and Proteins for Applications in (Bio)chemistry and Medicine

Autor: Sarah Lentink, David E. Salazar Marcano, Mhamad Aly Moussawi, Tatjana N. Parac‐Vogt

Publikováno v: Angewandte Chemie International Edition.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::103a72366ebf2f72e909e28572ee8abd
https://doi.org/10.1002/anie.202303817

Rational Synthesis of Elusive Organic-Inorganic Hybrid Metal-oxo Clusters: Formation and Post-functionalization of Hexavanadates

Autor: David E. Salazar Marcano, Givi Kalandia, Mhamad Aly Moussawi, Kristof Van Hecke, Tatjana N. Parac-Vogt

Paving the way towards new functional materials relies increasingly on the challenging task of forming organic-inorganic hybrid compounds. In that regard, discrete atomically-precise metal-oxo nanoclusters have received increasing attention due to th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7d28d402b50f6b53cf3e5e8193234de
https://doi.org/10.26434/chemrxiv-2023-m3k16

Investigation of the protonation state of the macrocyclic {HnP8W48O184} anion by modeling 183W NMR chemical shifts

Autor: Marc Henry, Francis Taulelle, Emmanuel Cadot, Mohamed Haouas, Sébastien Floquet, Manal Diab, Mhamad Aly Moussawi

Publikováno v: New Journal of Chemistry. 41:6112-6119

A semi-empirical approach based on the partial charge formalism has been used to calculate 183W NMR chemical shifts in polyoxotungstates (POTs). Good consistency between calculations and experimental measurements allowed determining the main effectiv

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d2ede6d305dbbde367955e1308206ca4
https://doi.org/10.1039/c7nj00915a

Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin

Autor: Yuri V. Mironov, David Landy, Pavel A. Abramov, Emmanuel Cadot, Sébastien Floquet, Michael A. Shestopalov, Nikolay G. Naumov, Mohamed Haouas, Kamil Lang, Mhamad Aly Moussawi, Clément Falaise, Stéphane Cordier, Maxim N. Sokolov, Kaplan Kirakci, Konstantin A. Brylev, Anton A. Ivanov, Yann Molard

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, 2018, 24 (51), pp.13467-13478. ⟨10.1002/chem.201802102⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2018, 24 (51), pp.13467-13478. ⟨10.1002/chem.201802102⟩

Water-soluble salts of anionic [Re6 Q8 (CN)6 ]4- (Q=S, Se, Te) chalcogenide octahedral rhenium clusters react with γ-cyclodextrin (γ-CD) producing a new type of inclusion compounds. Crystal structures determined through single-crystal X-ray diffrac

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9c16db67739ba53b60794b8775bde5c
https://univ-rennes.hal.science/hal-01863768/document

pH-Controlled One Pot Syntheses of Giant Mo 2 O 2 S 2 -Containing Seleno-Tungstate Architectures

Autor: Cristian Vicent, Sébastien Floquet, Mhamad Aly Moussawi, Pavel A. Abramov, Emmanuel Cadot, Mohamed Haouas

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2018, 57 (1), pp.56-63. ⟨10.1021/acs.inorgchem.7b01644⟩

Self-assembly reactions of Na2WO4, SeO2/SeO32–, and [Mo2O2(μ-S)2(H2O)6]2+ give, depending on the pH value, two new large polyoxometalate complexes: i.e., [(γ-Se2W14O52)3(Mo2O2(μ-S)2(H2O)2)6]24– (1) isolated at pH 3.5 and [(γ-Se2W14O52)4(WO3(H

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::492d3e26ca1f0343be4557ff2502477c
https://hal.archives-ouvertes.fr/hal-02335584