Výsledky vyhledávání - "Methylarsine"

The rotational spectrum of Methylarsine

Autor: Jean Demaison, Natalja Vogt, Harald Møllendal, Roman A. Motiyenko, Laurent Margulès, Jean-Claude Guillemin, Vadim V. Ilyushin

Publikováno v: Journal of Molecular Structure
Journal of Molecular Structure, 2020, 1213, pp.128037. ⟨10.1016/j.molstruc.2020.128037⟩
Journal of Molecular Structure, Elsevier, 2020, 1213, pp.128037. ⟨10.1016/j.molstruc.2020.128037⟩

The rotational spectrum of an organoarsenic compound, methylarsine, CH 3 AsH 2 , was studied in the frequency range 10–80 GHz using the Stark-modulated spectrometer in Oslo, and in the frequency range 150–660 GHz using the Lille spectrometer. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3edeb56156171a672de91033b9b0a050
https://univ-rennes.hal.science/hal-02569942

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Rovibrational spectroscopic constants and anharmonic force fields of CH3AsH2 and CH2AsH3: An study

Autor: Yanli Liu, Shanshan Ma, Chuan-Lu Yang, Lihan Chi, Mei-Shan Wang, Xiaomin Song

Publikováno v: Chemical Physics Letters. 780:138917

The spectroscopic constants and anharmonic force fields of Methylarsine and its isomer are systematically studied by B3LYP, CAM-B3LYP, M06-2X methods utilizing the cc-PVTZ and cc-PVQZ basis sets. The calculated equilibrium geometries, fundamental fre

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b4ac18360b821f980f17325b1a9b26a4
https://doi.org/10.1016/j.cplett.2021.138917

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Akademický článek

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Heterometallic heterochalcogenmethylarsenide clusters: Synthesis, molecular structures, and thermolysis

Autor: A. A. Pasynskii, Zh. V. Dobrokhotova, S. S. Shapovalov, N. A. Pushkarevskii, K. A. Lysenko, S. N. Konchenko

Publikováno v: Russian Journal of Coordination Chemistry. 35:112-119

Reactions of the arsinechalcogenide complexes [Fe3(μ3-X)(μ3-AsCH3)(CO)9] (X = Se (Ia) or Te (Ib)) with (PPh3)2Pt(PhC≡CPh) (transmetalation reaction) and Cp2Cr2(SCME3)2S (Cp = π-C5H5) (photochemical reaction) gave the heterometallic (heterochalco

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c3f86aa93f01e01ec719037c97bd1d9d
https://doi.org/10.1134/s1070328409020055

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Mechanism of formation of heteroleptic nickel(II)–arsine complexes from homoleptic precursors

Autor: Lyall R. Hanton, Charles R. Clark, David A. McMorran, David A. Buckingham

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1165-1168

The reaction of square-pyramidal [Ni(bdmma) 2 ] 2+ {bdmma = bis[2-(dimethylarsino)phenyl]methylarsine } with either free pdma [o-phenylenebis(dimethylarsine)] or square-planar [Ni(pdma) 2 ] 2+ gave five-co-ordinate [Ni(bdmma)(pdma)] 2+ . Kinetic stud

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::31526f2b92ca33dfd88b21fb3d48dd22
https://doi.org/10.1039/a607837k

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Metabolism of arsenic in primary cultures of human and rat hepatocytes

Autor: L.M. Del Razo, Changqing Wang, William R. Cullen, David J. Thomas, G. Hamilton, Edward L. LeCluyse, Miroslav Styblo

Publikováno v: Chemical research in toxicology. 12(7)

The liver is considered a major site for methylation of inorganic arsenic (iAs). However, there is little data on the capacity of human liver to methylate iAs. This work examined the metabolism of arsenite (iAs(III)), arsenate (iAs(V)), methylarsine

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::949eccc0fd9ddefbe26cdc2eeb8bee4a
https://pubmed.ncbi.nlm.nih.gov/10409394

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Determination of Dimethylarsinic Acid by Hydride Generation - Gas Phase Molecular Absorption Spectrometry

Autor: Sanz-Asensio, J., Pérez-Clavijo, M., Martínez-Soria, M.T.

Publikováno v: RIUR: Repositorio Institucional de la Universidad de La Rioja
Universidad de La Rioja (UR)
RIUR. Repositorio Institucional de la Universidad de La Rioja
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A method is described for the determination of dimethylarsinic and monomethylarsonous acids. The procedure involves NaBH4 reduction of the arsenic compounds to the corresponding gaseous arsines. After generation, the hydrides are collected in a liqui

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cc8f18db100d631be308e2f6bca52ab0
https://investigacion.unirioja.es/documentos/5bbc69ccb750603269e821a1

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