Zobrazeno 1 - 10
of 107
pro vyhledávání: '"Metal carbon dioxide complex"'
Autor:
Albert Paparo, Jun Okuda
Publikováno v:
Journal of Organometallic Chemistry. 869:270-274
Chemistry freshmen learn to distinguish between nitrate NO 3 − and nitrite NO 2 − or sulfate SO 4 2− and sulfite SO 3 2− , but how many would know about carbonite CO 2 2− in contrast to carbonate CO 3 2− ? This is not surprising for an an
Autor:
Kyle A. Grice
Publikováno v:
Coordination Chemistry Reviews. 336:78-95
The field of carbon dioxide reduction by homogeneous early transition complexes (groups 3–7) is reviewed. Many reactions with CO2 have been studied with late transition metal complexes (groups 8–10), and significant progress has been made in deve
Autor:
Geoffrey A. Ozin, Hong Wang, Chenxi Qian, Aron Walsh, Mireille Ghoussoub, Young Feng Li, Keith T. Butler, Jia Jia, Yuchan Dong
Publikováno v:
Chemical Society Reviews. 46:4631-4644
Metal oxides with their myriad compositions, structures and bonding exhibit an incredibly diverse range of properties. It is however the defects in metal oxides that endow them with a variety of functions and it is the ability to chemically tailor th
Recent advances in metal-free catalysts for the synthesis of cyclic carbonates from CO2 and epoxides
Autor:
Xian Gao, Na Fan, Lan Donghui, Shuang-Feng Yin, Ping Zhang, Lang Chen, Chak-Tong Au, Ying Wang
Publikováno v:
Chinese Journal of Catalysis. 37:826-845
The aim of “green chemistry” and “atom economy” is to utilize carbon dioxide and replace harmful reactants such as CO and phosgene for the production of cyclic carbonates. In this paper, metal-free catalysts including organic bases, ionic liq
Publikováno v:
European Journal of Inorganic Chemistry. 2016:4358-4362
A metal–organic framework (MOF) based on (bpy)Re(CO)3Cl-containing elongated dicarboxylate ligands and Zr6(µ3-O)4(µ3-OH)4 clusters was synthesized and used as an effective single-site catalyst to photochemically reduce carbon dioxide to carbon mo
Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
Publikováno v:
Bulletin of the Chemical Society of Japan. 89:113-124
Methoxy-substituted PNP–iridium(III) complexes and pyrazine-based PNP–iridium(III) complexes were developed and used to hydrogenate carbon dioxide in the presence of triethanolamine as a base. The ...
Autor:
Tohru Yamada, Kohei Sekine
Publikováno v:
Chemical Society Reviews. 45:4524-4532
Silver-catalyzed reactions are some of the important methodologies in organic chemistry. Since 2007, a new application of silver catalysts has been emerging. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl al
Publikováno v:
Angewandte Chemie (International ed. in English). 56(36)
Herein a non-precious transition-metal catalyst system for the selective synthesis of dialkoxymethane ethers from carbon dioxide and molecular hydrogen is presented. The development of a tailored catalyst system based on cobalt salts in combination w
Autor:
Vy M. Dong, Charles S. Yeung
Publikováno v:
Topics in Catalysis. 57:1342-1350
Developing more green and sustainable strategies for organic synthesis is an important modern challenge. Although carbon dioxide is an attractive reagent, because of its availability, the low reactivity of this small molecule renders it challenging t
Autor:
Marvin Johnson, Ola F. Wendt
Publikováno v:
Journal of Organometallic Chemistry. 751:213-220
The catalytic incorporation of CO2 into value-added chemicals to form e. g. carboxylic acids and carbonates is highly interesting due to the abundance, non-toxicity and low cost of carbon dioxide. Currently, palladium is one of the most exploited tra