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pro vyhledávání: '"Mercury(II) cyanide"'
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Autor:
Haseeba Sadaf, Sarfaraz Ahmed Bashir, Muhammad Awais Bin Altaf, Helen Stoeckli-Evans, Seerat-ur-Rehman, Saeed Ahmad
Publikováno v:
Crystallography Reports. 58:692-696
Two mercury(II) complexes containing cyanide and, N,N′-diethylthiourea (detu) and N,N′-dipropylthiourea (dprtu) ligands, [(detu)2Hg(CN)2] (1) and [(dprtu)2Hg(CN)2] (2), respectively, have been prepared and characterized by X-ray crystallography.
Autor:
Daniel B. Leznoff, Jasmine L. Korčok
Publikováno v:
Polyhedron. 52:72-77
Crystals of HgCN(NO3) were prepared by the reaction of Hg(CN)2 in nitric acid. Single crystal X-ray structures of both HgCN(NO3) and Hg(CN)2 were obtained at 100, 205, 295 and 395 K (or 375 K for Hg(CN)2); both structures have been previously reporte
Autor:
Mohammed Fettouhi, Muhammad Monim-ul-Mehboob, Anvarhusein A. Isab, M. Nasiruzzaman Shaikh, Mohammed I.M. Wazeer, Bassem A. Al-Maythalony, Saeed Ahmad
Publikováno v:
Journal of Coordination Chemistry. 65:2074-2086
Mercury cyanide complexes of alkyldiamines (1–6), [Hg(L)(CN)2] (where L = en (1,2-diaminoethane), pn (1,3-diaminopropane), N-Me-en, N, N′-Me2-en, N, N′-Et2-en, and N, N′-ipr2-en), have been synthesized and characterized by elemental analysis,
Autor:
Saeed Ahmad, Seik Weng Ng, S. A. Bashir, M. I. Khan, Islam Ullah Khan, Mehmet Akkurt, Muhammad Mufakkar, Shahzad Sharif, Haseeba Sadaf
Publikováno v:
Journal of Structural Chemistry. 53:151-155
Two mercury(II) cyanide complexes of N-ethylthiourea (Ettu) and N-propylthiourea (Prtu) ligands, [Hg(Ettu)(2)(CN)(2)] (1) and [Hg(Prtu)(2)(CN)(2)] (2), were prepared and their crystal structures were determined by X-ray crystallography. In both struc
Autor:
Anvarhusein A. Isab, Mohammed Fettouhi, Atif Fazal, Saqib Ali, Muhammad Riaz Malik, Saeed Ahmad
Publikováno v:
Russian Journal of Coordination Chemistry. 37:180-185
Mercury(II) cyanide complexes of thioureas (Tu), N-methylthiourea (MeTu), and N,N′-dimethylthiourea (DmTu)) have been prepared and characterized by IR and NMR (1H and 13C) spectroscopy, and the crystal structure of one of them was determined by X-r
Autor:
Abdul Rahman Al-Arfaj, Muhammad Altaf, Muhammad Riaz Malik, Saqib Ali, Anvarhusein A. Isab, Helen Stoeckli-Evans, Saeed Ahmad
Publikováno v:
Journal of Chemical Crystallography. 40:1175-1179
The title compound was prepared by reacting mercury(II) cyanide and tetramethylthiourea (Tmtu) in the molar ratio of 1:1.75. It was characterized by IR and NMR (1H and 13C) spectroscopy, and X-ray crystallography. The appearance of a band around 2,20
Publikováno v:
Inorganic Chemistry Communications. 12:540-543
Mercury(II) cyanide reacts with 1,4-diaminobutane (bn) at a 1:1 ratio forming a polymeric complex [(bn)Hg(CN)2]∞ in which (bn) acts as a bridge between the Lewis acid Hg(CN)2 moieties. The metal complex coordination sphere Hg[(CN)2N2] is best descr
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 46:207-211
The complexation of mercury(II) cyanide with macrocyclic ligands 15-crown-5,18-crown-6 and dibenzo-24-crown-8 in dimethylsulfoxide was studied using199Hg NMR measurements. No significant complexation with 15-crown-5was observed. The stability constan
Publikováno v:
Journal of Molecular Structure. :65-68
Evidence based on the IR and Raman spectral features of HE(CN)(2) in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from