Zobrazeno 1 - 10 of 87 pro vyhledávání: '"Mercedes Medio-Simón"'
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Akademický článek
Pauson–Khand reaction of fluorinated compounds
Autor: Jorge Escorihuela, Daniel M. Sedgwick, Alberto Llobat, Mercedes Medio-Simón, Pablo Barrio, Santos Fustero
Publikováno v: Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 1662-1682 (2020)
The Pauson–Khand reaction (PKR) is one of the key methods for the construction of cyclopentenone derivatives, which can in turn undergo diverse chemical transformations to yield more complex biologically active molecules. Despite the increasing ava
Externí odkaz: https://doaj.org/article/7e7c0875644744019119f2c7659a0b06
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3
Intramolecular rhodium-catalysed [2 + 2 + 2] cycloaddition of linear chiral N-bridged triynes: straightforward access to fused tetrahydroisoquinoline core
Autor: Alberto Llobat, Jorge Escorihuela, Carmen Ramírez de Arellano, Santos Fustero, Mercedes Medio-Simón
Publikováno v: Organic & Biomolecular Chemistry. 20:2433-2445
Rhodium-catalyzed intramolecular [2 + 2 + 2] cycloaddition of linear chiral triynes having 4-atom tethers leads to, in a single step, complex tetrahydroisoquinolines having central chirality.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b37b50ffbc1798a36ca04f69355295e7
https://doi.org/10.1039/d2ob00340f
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4
Pauson–Khand reaction of fluorinated compounds
Autor: Alberto Llobat, Daniel M. Sedgwick, Santos Fustero, Pablo Barrio, Mercedes Medio-Simón, Jorge Escorihuela
Publikováno v: Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 1662-1682 (2020)
WOS:000548541400001
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
RUO: Repositorio Institucional de la Universidad de Oviedo
Universidad de Oviedo (UNIOVI)
The Pauson–Khand reaction (PKR) is one of the key methods for the construction of cyclopentenone derivatives, which can in turn undergo diverse chemical transformations to yield more complex biologically active molecules. Despite the increasing ava
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::153c582b376b7247f5017079f0ccb416
http://europepmc.org/articles/PMC7372243
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8
Vinyl Fluorides: Competent Olefinic Counterparts in the Intramolecular Pauson–Khand Reaction
Autor: Natalia Mateu, Pablo Barrio, Mercedes Medio-Simón, Inés López, Santos Fustero, Raquel Román
Publikováno v: Organic Letters. 21:2569-2573
Despite the great advances achieved in the Pauson-Khand reaction and the ever-increasing demand for fluorinated compounds, the use of vinyl fluorides as olefinic counterparts in the above-mentioned transformation had been completely overlooked. Herei
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60c027a1c7124ffbdac43e30174f4415
https://doi.org/10.1021/acs.orglett.9b00509
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10
Diastereoselectivity of the Addition of Propargylic Magnesium Reagents to Fluorinated Aromatic Sulfinyl Imines
Autor: Mercedes Medio-Simón, Santos Fustero, Jorge Escorihuela, Alberto Llobat
Publikováno v: Organic letters. 23(9)
The addition of propargylmagnesium bromide to fluorinated aromatic sulfinyl imines gave homopropargyl amines with total regio- and diastereoselection. Complete reversal of diastereoselectivity can be achieved in some cases using coordinating (THF) or
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67a826cc177575c2cf7dc0f819195d93
https://pubmed.ncbi.nlm.nih.gov/33881896
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