Zobrazeno 1 - 10
of 238
pro vyhledávání: '"Melvyn V. Sargent"'
Autor:
Dayar Arbain, Melvyn V. Sargent
Publikováno v:
ASEAN Journal on Science and Technology for Development, Vol 4, Iss 1, Pp 41-44 (2017)
A Preliminary Investigation of The Alkaloid of Phoebe Lanceolata
Externí odkaz:
https://doaj.org/article/a2f6258002624bffa41fb7755068090a
Autor:
Robert W. Baker, Simon O. Rea, Elisabeth M.C. Schenkelaars, Melvyn V. Sargent, Tjitjik Srie Tjahjandarie, Angela Totaro
Publikováno v:
Tetrahedron. 61:3733-3743
Racemic 1-(1′-isoquinolinyl)-2-naphthalenemethanol rac-12 was prepared through a ligand coupling reaction of racemic 1-(tert-butylsulfinyl)isoquinoline rac-7 with the 1-naphthyl Grignard reagent 10. Resolution of rac-12 was achieved through chromat
Publikováno v:
Tetrahedron Letters. 40:3475-3478
Schmidt reaction of ( S )-1-(2′, 4′, 6-trimethoxy-4, 6′-dimethylbiphenyl-2-yl)ethanone 8 furnished the expected amide 9 (43%) accompanied by ( S )-2, 7′-dimethoxy-3′, 5′, 6-trimethylspiro[cyclohexa-2, 5-diene-1, 1′-(1 H )isoindole]-4-on
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :3029-3038
Addition of 7-benzyloxy-4,5-dimethoxy-1-naphthol 3 as its triisopropoxytitanium naphtholate to (2R, 1′R or S)-2-(1′-ethoxyethoxy)propanal 4 afforded solely (1S, 2R, 1″R or S)-1-(7′-benzyloxy-4′,5′-dimethoxy-1′-hydroxy-2′-naphthyl)-2-(
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :1333-1338
The synthesis of a number of 2-substituted 1-(tert-butylsulfinyl)naphthalenes is described and the free energies of activation (ΔG ‡ = 50.0–80.7 kJ mol–1) for their stereomutation about the S–Ar bonds have been determined. It is shown that t
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :2537-2540
The alkaloid content of two different collections of Ophiorrhiza blumeana Korth. (Rubiaceae) was investigated. The first collection yielded the known alkaloid bracteatine 5 and two new alkaloids ophiorrhizine-12-carboxylate 6 and blumeanine 7. The se
Publikováno v:
Tetrahedron Letters. 37:7851-7854
Chiral compounds 16 and 17, precursors to the aphid insect pigment derivatives, have been prepared in good to high yield, with complete control of the diastereoselectivity at the newly-created chiral centre C-1, through the use of metal phenolates de
Autor:
Melvyn V. Sargent, Allan H. White, Geoffrey R. Pocock, David C. R. Hockless, Alexander N. Sobolev, Brian W. Skelton, E. Twiss, Robert W. Baker
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :2615-2629
1-(Alkyl- or aryl-sulfinyl)naphthalenes activated by electron-withdrawing substituents at the 2-position undergo substitution reactions on treatment with Grignard reagents. Evidence suggesting that these transformations proceed through ligand-couplin
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 60:o86-o88
The structure of the title compound, C20H20O8, which was extracted from Rhodomyrtus tomentosa, confirms the connectivity and is consistent with the results from spectroscopy. The structure, notable for the crowded sequence of (3′,4′,5′) trime
Autor:
Brian W. Skelton, Simon O. Rea, Allan H. White, Robert W. Baker, Melvyn V. Sargent, Elisabeth M.C. Schenkelaars
Publikováno v:
Tetrahedron: Asymmetry. 5:45-48
Racemic 1-(1-isoquinolinyl)-2-naphthalenemethanol 6 has been prepared through a ligand coupling reaction of racemic 1-( tert -butylsulfinyl)isoquinoline 2 with the 1-naphthyl Grignard reagent 4 . Resolution of the ligand 6 was achieved through chroma