Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Melanie Riethmann"'
Publikováno v:
Chemical Science. 14:2275-2288
An easy-to-perform approach to assess and quantify steric properties of Lewis acids is reported. The novel LAB-Rep model (Lewis acid/base repulsion model) is introduced, which judges steric repulsion in Lewis acid/base pairs.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ac398cec64c5cb7e89d158c6a73d59e0
https://doi.org/10.1039/d3sc00037k
https://doi.org/10.1039/d3sc00037k
Publikováno v:
Dalton Transactions.
A case study on the selective dehydrogenation of Cp* (Cp* = C5Me5) aluminum and gallium hydrides using N-heterocyclic carbenes and the cyclic(alkyl)(amino)carbene cAACMe is presented.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a3ddb2869d623e9a7e438c320c52d9af
https://doi.org/10.1039/d3dt00765k
https://doi.org/10.1039/d3dt00765k
Publikováno v:
European Journal of Inorganic Chemistry. 2020:4015-4023
The NHC alane and gallane adducts (NHC)·AlH\(_{2}\)I (NHC = Me\(_{2}\)Im\(^{Me}\) 7, iPr\(_{2}\)Im 8, iPr\(_{2}\)Im\(^{Me}\) 9) and (NHC)·GaH\(_{2}\)I (NHC = Me\(_{2}\)Im\(^{Me}\) 10, iPr\(_{2}\)Im\(^{Me}\) 11, Dipp\(_{2}\)Im 12; R\(_{2}\)Im = 1,3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f73a61f9ac037520ae2d1c0b8e9d431
https://doi.org/10.1002/ejic.202000720
https://doi.org/10.1002/ejic.202000720