Zobrazeno 1 - 10 of 17 pro vyhledávání: '"Melanie J. Harvey"'
1
Stability of cyclopentadienyl aryloxide complexes of calcium and barium
Autor: Timothy P. Hanusa, Stephen C. Chmely, David J. Burkey, Melanie J. Harvey
Publikováno v: Journal of Alloys and Compounds. 488:528-532
The synthesis of mono(cyclopentadienyl)aryloxide complexes of calcium and barium has been investigated. The reaction of ICa(ODipp)(thf) 4 (Odipp = [2,6-iPr-OC 6 H 3 O] ― ) with K[C 5 Me 5 ], (Cp 3Si ) 2 Ca (Cp 3Si = C 5 (SiMe 3 ) 3 H 2 ) with K[ODi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d9c5efb7f2056ec032abdb19145adee8
https://doi.org/10.1016/j.jallcom.2008.08.084
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2
A Homologous Series of Base‐Free Organo(alkaline‐earth) Metallocenes: Synthesis and Molecular Structures of [1,2,4‐(SiMe 3 ) 3 C 5 H 2 ] 2 (Ca, Sr, Ba)
Autor: Timothy P. Hanusa, Keith T. Quisenberry, Victor G. Young, Melanie J. Harvey
Publikováno v: European Journal of Inorganic Chemistry. 2003:3383-3390
Bis[1,2,4-tris(trimethylsilyl)cyclopentadienyl] complexes [1,2,4-(SiMe3)3C5H2]2Ae [(Cp3Si)2Ae; Ae = Ca (1), Sr (2), Ba (3)] are isolated from the 2:1 reaction of K[Cp3Si] and AeI2 in diethyl ether. Under the same reaction conditions used for the heav
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::139616c323ec21a10c3e34fa70df7ac7
https://doi.org/10.1002/ejic.200300284
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3
Salen-Type Compounds of Calcium and Strontium
Autor: Sean Parkin, Fredrik L. Nordström, Melanie J. Harvey, David A. Atwood, Mario Sánchez
Publikováno v: Inorganic Chemistry. 41:5397-5402
Salen complexes of the heavy alkaline-earth metals, calcium and strontium, were prepared by the reaction of various salen(t-Bu)H(2) ligands with the metals in ethanol. Six new calcium and strontium compounds, [Ca(salen(t-Bu))(HOEt)(2)(thf)] (1), [Ca(
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0abf213ee02e0941cc25d9227946720f
https://doi.org/10.1021/ic020101t
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4
Alkali Metals: Organometallic Chemistry
Autor: Melanie J. Harvey
Publikováno v: Encyclopedia of Inorganic and Bioinorganic Chemistry
Organolithium complexes, like the organomagnesium Grignard Reagents, are important reactants in organic synthesis. The similarity in structure, bonding, and reactivity of organolithium and -magnesium compounds exemplifies the common chemistry exhibit
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a660a35a04cd300b8972296b12cfe225
https://doi.org/10.1002/9781119951438.eibc0004.pub2
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5
Formation and crystal structures of a monomer–dimer pair of mono(cyclopentadienyl)calcium complexes, [C5(t-Bu)3H2]2CaI(THF)2 and {[C5(t-Bu)3H2]2CaI(THF)}2
Autor: Timothy P. Hanusa, Melanie J. Harvey, Victor G. Young
Publikováno v: Journal of Organometallic Chemistry. 626:43-48
The mono(cyclopentadienyl)calcium iodide complex [{(Cp3T)CaI(THF)x}n] (Cp3T=[C5(t-Bu)3H2]−) is generated from the 1:1 reaction of K[Cp3T] and CaI2 in THF. No redistribution into [(Cp3T)2Ca] and CaI2(THF)n is observed in THF solution. The mono(ring)
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::aa75bf72a336e78339f7709c6011dd43
https://doi.org/10.1016/s0022-328x(01)00658-1
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6
Group 13 Compounds Incorporating Salen Ligands
Autor: David A. Atwood, Melanie J. Harvey
Publikováno v: Chemical Reviews. 101:37-52
In a previous review it was predicted that "the reactivity of five-coordinate complexes would certainly be different than that of the four-coordinate derivatives". Structurally and spectroscopically, there is very little difference in the higher-coor
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c178508519d33810555be4e528894a1
https://doi.org/10.1021/cr990008v
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7
Mono(cyclopentadienyl) Complexes of Calcium, Strontium, and Barium, {[C5(SiMe3)3H2](Ca,Sr,Ba)I(thf)n}x. Influence of Alkali-Metal Cations on Ligand Exchange Reactions
Autor: Melanie J. Harvey and, Timothy P. Hanusa
Publikováno v: Organometallics. 19:1556-1566
Reaction of the alkali-metal cyclopentadienide MCp‘ with an alkaline-earth dihalide (AeX2) in ethers is usually an efficient route to group 2 cyclopentadienyl complexes Cp‘nAeX2-n. This is not true for every Cp‘/Ae combination, however, and the
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::946b6df0d6c53d5537a2d9775eed4799
https://doi.org/10.1021/om991003r
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8
Structural characterization of the columnar alkali metal cyclopentadienide [K{C5H2(SiMe3)3-1,2,4}]∞†
Autor: Maren Pink, Timothy P. Hanusa, Melanie J. Harvey
Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1128-1130
Unsolvated 1,2,4-tris(trimethylsilyl)cyclopentadienyl potassium (K[Cp3Si]) crystallizes as a base-free “super-sandwich” of alternating potassium ions and Cp′ rings. The polymeric chains in the structure are not connected as in other unsolvated
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ed567c9c862457db4447e836bbd1d0fe
https://doi.org/10.1039/b009359i
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10
Synthesis and Crystal Structure of the Bis(allyl)calcium Complex [Ca{C3(SiMe3)2H3}2⋅(thf)2]
Autor: Melanie J. Harvey, Victor G. Young, Timothy P. Hanusa
Publikováno v: Angewandte Chemie International Edition. 38:217-219
Two η3-allyl ligands in an anti configuration are present in the title compound (structure depicted). Even though the Ca−C bonds are about the length expected for cyclopentadienyl complexes, the bis(trimethylsilyl)allyl anion displays hydrogen-ato
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9338600b1be73456f06b40b431dc4e61
https://doi.org/10.1002/(sici)1521-3773(19990115)38:1/2<217::aid-anie217>3.0.co
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