Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Melania Prado Merini"'
Autor:
Yuta Hioki, Matteo Costantini, Jeremy Griffin, Kaid C. Harper, Melania Prado Merini, Benedikt Nissl, Yu Kawamata, Phil S. Baran
Publikováno v:
Science. 380:81-87
The Kolbe reaction forms carbon-carbon bonds through electrochemical decarboxylative coupling. Despite more than a century of study, the reaction has seen limited applications owing to extremely poor chemoselectivity and reliance on precious metal el
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5ff6b16f57f994f735bf3c58d6644a94
https://doi.org/10.1126/science.adf4762
https://doi.org/10.1126/science.adf4762
Publikováno v:
Accounts of Chemical Research. 55:2180-2190
ConspectusA decisive factor for obtaining high yields and selectivities in organic synthesis is the choice of the proper solvent. Solvent selection is often guided by the intuitive understanding of transition state-solvent interactions. However, quan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eda069819ac83eb861ee210495424580
https://doi.org/10.1021/acs.accounts.2c00151
https://doi.org/10.1021/acs.accounts.2c00151
Publikováno v:
Angewandte Chemie (International Ed. in English)
The equilibrium between benzene oxide (1) and oxepin (2) is of large importance for understanding the degradation of benzene in biological systems and in the troposphere. Our studies reveal that at cryogenic temperatures, this equilibration is govern
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::394da6dfdfec59957898b95e0c57c83f
https://doi.org/10.1002/ange.202010452
https://doi.org/10.1002/ange.202010452
Publikováno v:
Chemical Science
For many thermal reactions, the effects of catalysis or the influence of solvents on reaction rates can be rationalized by simple transition state models. This is not the case for reactions controlled by quantum tunneling, which do not proceed via tr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::b642875c8ddecb30edc5e2424c5b3d78
https://pubmed.ncbi.nlm.nih.gov/34522298
https://pubmed.ncbi.nlm.nih.gov/34522298
Publikováno v:
Angewandte Chemie International Edition. 59
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::964609e470d43689a5a7b7b9e761c9f7
https://doi.org/10.1002/anie.202084661
https://doi.org/10.1002/anie.202084661