Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Megan A. Whitefoot"'
Publikováno v:
Chemistry – A European Journal. 27:18054-18057
Two Np(III) halides, NpI3 (THF)4 and NpBr3 (THF)4 , have been prepared and isolated in high yields as described in this work. Starting with neptunia (NpO2 ), NpCl4 (DME)2 was first generated in an updated, higher yielding synthesis than what was prev
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::58fc7d3ef04712c1d42ed31219ad284b
https://doi.org/10.1002/chem.202103265
https://doi.org/10.1002/chem.202103265
Autor:
Joseph M. Sperling, Bonnie E. Klamm, Evan Warzecha, Alyssa N. Gaiser, Thomas E. Albrecht-Schönzart, Cory J. Windorff, Megan A. Whitefoot
Publikováno v:
Inorganic Chemistry. 60:476-483
The mellitate ion is relevant in spent nuclear fuel processing and is utilized as a surrogate for studying the interactions of f elements with humic acids. A wealth of different coordination modes gives the potential for diverse structural chemistry
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::79f6226227aa93d96a1064a1f6fda9e6
https://doi.org/10.1021/acs.inorgchem.0c03293
https://doi.org/10.1021/acs.inorgchem.0c03293
Autor:
Dumitru-Claudiu Sergentu, Eva Zurek, Frankie D. White, Paul Kögerler, Kenneth Hanson, Thomas E. Albrecht-Schönzart, Megan A. Whitefoot, Xiaoyu Wang, Manfred Speldrich, Alexander T. Chemey, Alyssa N. Gaiser, Brian N. Long, Cory J. Windorff, Cristian Celis-Barros, Bonnie E. Klamm, Joseph M. Sperling, Drake Beery, Jochen Autschbach, Evan Warzecha
Publikováno v:
Nature. 583:396-399
Curium is unique in the actinide series because its half-filled 5f 7 shell has lower energy than other 5f n configurations, rendering it both redox-inactive and resistant to forming chemical bonds that engage the 5f shell1–3. This is even more pron
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::16d73e3f9d8ca88e975bb65a3ace0fe7
https://doi.org/10.1038/s41586-020-2479-2
https://doi.org/10.1038/s41586-020-2479-2
Autor:
Joseph M. Sperling, Alexander T. Chemey, Megan A. Whitefoot, Joanna G Campbell, Bonnie E. Klamm, Thomas E. Albrecht-Schmitt, Brian N. Long, Alyssa N. Gaiser, Cory J. Windorff
Publikováno v:
Inorganic Chemistry. 59:3085-3090
The aqueous reaction of mellitic acid (H6mell) with 242PuBr3·nH2O forms two plutonium mellitates, 242Pu2(mell)(H2O)9·H2O (Pu-1α) and 242Pu2(mell)(H2O)8·2H2O (Pu-1β). These compounds are compared to the isomorphous lanthanide mellitates with simi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a646d77bec0cb149e8f23054250674c
https://doi.org/10.1021/acs.inorgchem.9b03432
https://doi.org/10.1021/acs.inorgchem.9b03432
Autor:
Joseph M. Sperling, Suzanne C. Bart, Thomas E. Albrecht-Schönzart, Ryan Baumbach, Robert F. Higgins, Megan A. Whitefoot, Shane S. Galley, Scott A. Pattenaude, William Nelson, Tyler S. Collins, Carlo Alberto Gaggioli, Matthias Zeller, Debmalya Ray, Laura Gagliardi, Eric J. Schelter, Yusen Qiao
Publikováno v:
Inorganic chemistry. 60(20)
Using a redox-active dioxophenoxazine ligand, DOPO (DOPO = 2,4,6,8-tetra-tert-butyl-1-oxo-1H-phenoxazine-9-olate), a family of actinide (U, Th, Np, and Pu) and Hf tris(ligand) coordination compounds was synthesized. The full characterization of these
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b13bfbb1024d83c22cae52463a19e427
https://pubmed.ncbi.nlm.nih.gov/34569783
https://pubmed.ncbi.nlm.nih.gov/34569783
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 27(72)
Two Np(III) halides, NpI
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::2767f472860297d8b00b84930e2d1ea7
https://pubmed.ncbi.nlm.nih.gov/34643978
https://pubmed.ncbi.nlm.nih.gov/34643978
Autor:
Joseph M. Sperling, Alyssa N. Gaiser, Evan Warzecha, Megan A. Whitefoot, Frankie D. White, Cory J. Windorff, Todd N. Poe, Bonnie E. Klamm, Thomas E. Albrecht-Schönzart
Publikováno v:
Inorganic chemistry. 59(15)
In this study, the synthesis, characterization, and pressure response of a 1D californium mellitate (mellitate = 1,2,3,4,5,6-benzenehexacarboxylate) coordination polymer, Cf2(mell)(H2O)10·4H2O (Cf-...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59055e16e99d6216c054c6ff48729802
https://pubmed.ncbi.nlm.nih.gov/32648751
https://pubmed.ncbi.nlm.nih.gov/32648751
Autor:
Joseph M, Sperling, Evan J, Warzecha, Cristian, Celis-Barros, Dumitru-Claudiu, Sergentu, Xiaoyu, Wang, Bonnie E, Klamm, Cory J, Windorff, Alyssa N, Gaiser, Frankie D, White, Drake A, Beery, Alexander T, Chemey, Megan A, Whitefoot, Brian N, Long, Kenneth, Hanson, Paul, Kögerler, Manfred, Speldrich, Eva, Zurek, Jochen, Autschbach, Thomas E, Albrecht-Schönzart
Publikováno v:
Nature. 583(7816)
Curium is unique in the actinide series because its half-filled 5f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::89c8d064b93d98b028c3c3ed3e5d33fc
https://pubmed.ncbi.nlm.nih.gov/32669698
https://pubmed.ncbi.nlm.nih.gov/32669698
Dissertation/ Thesis
Autor:
Megan A Whitefoot (11198847)
The interest in understanding the f-block elements has been increasing because of the large applications of these elements across all fields of science and technology. The lanthanides are used in various technologies like car batteries and phone scre
