The sol–gel autocombustion as a route towards highly CO2-selective, active and long-term stable Cu/ZrO2 methanol steam reforming catalysts†

Autor: Andrew Doran, Albert Gili, Maximilian Watschinger, Bernhard Klötzer, Parastoo Delir Kheyrollahi Nezhad, Simon Penner, Marc Armbrüster, Aleksander Gurlo, Pengfei Cao, Marc Heggen, Kevin Ploner, Franz Kamutzki, Nicolas Köwitsch

Publikováno v: Materials Chemistry Frontiers
Materials chemistry frontiers, vol 5, iss 13
Materials chemistry frontiers 5(13), 5093-5105 (2021). doi:10.1039/D1QM00641J

The adaption of the sol–gel autocombustion method to the Cu/ZrO2 system opens new pathways for the specific optimisation of the activity, long-term stability and CO2 selectivity of methanol steam reforming (MSR) catalysts. Calcination of the same p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::18805ce8e23a0429cfc1e43682aeb0ac
http://europepmc.org/articles/PMC8238116

Mechanistic insights into the catalytic methanol steam reforming performance of Cu/ZrO2 catalysts by in situ and operando studies

Autor: Parastoo Delir Kheyrollahi Nezhad, Stefan Vanicek, Maximilian Watschinger, Lukas Schlicker, Christoph Thurner, Lei Zhang, Albert Gili, Bernhard Klötzer, Aleksander Gurlo, Eva-Maria Köck, Andrew Doran, Nicholas Köwitsch, Kevin Ploner, Thomas Götsch, Marc Armbrüster, Simon Penner, Wolfgang Wallisch

Publikováno v: Journal of Catalysis. 391:497-512

We assessed the catalytic properties of the Cu/ZrO2 interface in methanol and formaldehyde steam reforming (MSR and FSR) on powder catalysts by using a comparative approach with respect to the influence of the ZrO2 polymorph support structure (monocl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::36372bfba570ccd35ec6d48e841872f0
https://doi.org/10.1016/j.jcat.2020.09.018

Steering the methanol steam reforming reactivity of intermetallic Cu-In compounds by redox activation: stability

Autor: Kevin, Ploner, Andrew, Doran, Martin, Kunz, Albert, Gili, Aleksander, Gurlo, Nicolas, Köwitsch, Marc, Armbrüster, Johannes, Bernardi, Maximilian, Watschinger, Simon, Penner

Publikováno v: Catalysis Science & Technology

To compare the inherent methanol steam reforming properties of intermetallic compounds and a corresponding intermetallic compound–oxide interface, we selected the Cu–In system as a model to correlate the stability limits, self-activation and redo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::308f26a5d817516f60946f88c6e430fe
https://pubmed.ncbi.nlm.nih.gov/34457240