Zobrazeno 1 - 10
of 155
pro vyhledávání: '"Max T. Rogers"'
Autor:
John D. Roberts, Max T. Rogers
Publikováno v:
Journal of the American Chemical Society. 68
There is considerable evidence that compounds in which a cyclopropane ring is located adjacent to an unsaturated linkage, such as a carbonyl group or double bond, exhibit many of the physical and chemical properties characteristic of substances conta
Autor:
A. Kasi Viswanath, Max T. Rogers
Publikováno v:
The Journal of Chemical Physics. 75:4183-4191
Single crystals of RbCl, RbBr, and KCl doped with [Fe(CN)6]4− were grown from solution and ESR spectra of both x‐ and γ‐irradiated crystals were recorded over a wide temperature range. A number of Fe(I) radicals were obtained and identified by
Autor:
Max T. Rogers, Shaw‐Guang Huang
Publikováno v:
The Journal of Chemical Physics. 68:5601-5606
13C and 19F nuclear magnetic relaxation rates in liquid CFBr3 have been measured at 14.1 kG. By assuming that the motion of the molecules at low temperatures follows the classical diffusion model, the contributions of various relaxation mechanisms ha
Autor:
John R. Shock, Max T. Rogers
Publikováno v:
The Journal of Chemical Physics. 62:2640-2645
An ESR study of the [RhCl6]4− center in single crystals of AgCl has been made. The g values and chlorine hyperfine interactions observed for the axial chlorines are consistent with a d7 configuration and localization of the odd electron largely in
Publikováno v:
The Journal of Chemical Physics. 61:4808-4813
The crystal structure of bromomalonamide, HBrC(CONH2)2, has been determined from MoKa diffractometer data by use of Patterson and Fourier syntheses. The crystals are orthorhombic, Pnma, with cell constants at 22°C: a =9.487(3) A, b =11.294(4) A, c =
Autor:
David W. Wright, Max T. Rogers
Publikováno v:
The Journal of Chemical Physics. 63:909-914
Deuterium quadrupole coupling constants have been obtained for two symmetric‐top molecules in the liquid phase by combining NMR relaxation data with Raman line‐shape analysis of bands of A1 symmetry. The Raman lines have been corrected for vibrat
Autor:
Max T. Rogers, John R. Shock
Publikováno v:
Journal of Magnetic Resonance (1969). 18:157-166
An ESR study of the species [Co(CN)6]4− in irradiated single crystals of K3Co-(CN)6 and in irradiated NaCl and KCl doped with [Co(CN)6]3−, has been made, and the ESR parameters are reported. In addition, the ESR spectra of the same materials enri
Publikováno v:
Journal of Coordination Chemistry. 3:293-299
An ESR study of γ-irradiated pentacyanonitrosyl cobaltate (II) shows the presence of two paramagnetic species. One, with g∥ =2.005, g∥ =2.172, A∥ 81.3 and A∥ =-26.2 × 10−4 cm−1, is the well-known d 7 species Co(CN)5 3-. The second shows
Autor:
Shaw‐Guang Huang, Max T. Rogers
Publikováno v:
The Journal of Chemical Physics. 85:401-409
19F and 14N nuclear magnetic spin‐lattice relaxation rates in liquid CF3CN have been measured at 14.1 kG. From 14N relaxation rates, the correlation times of the tumbling motion were directly determined. By separating 19F relaxation rates into term
Publikováno v:
The Journal of Chemical Physics. 76:3078-3086
The self‐consistent field Xα multiple‐scattering (SCF–MS–Xα) method has been employed to study the electronic structure of (CrOCl4)−. The principal components of the g and hyperfine interaction tensors characterizing the electron spin res