Výsledky vyhledávání - "Maureen D. Kitchen"

Reduction–oxidation properties of organotransition-metal complexes. Part 2. The one-electron oxidation of tetracarbonyl(η-cyclopenta-dienyl) vanadium derivatives

Autor: Maureen D. Kitchen, Neil G. Connelly

Publikováno v: J. Chem. Soc., Dalton Trans.. :2165-2168

Cyclic-voltammetric studies in CH2Cl2 and MeCN have shown that [V(η-C5H5)(CO)3L]{1; L = PPh3, PMePh2, PEt3, P(NMe2)3, P[(OCH2)3CMe], and P(OPh)3} and [V(η-C5H5)(CO)2(dppe)](2; dppe = Ph2PCH2CH3PPh2) are oxidised at a platinum electrode to [V(η-C5H

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1190efe8a697fe0f55ab052e2445f3d5
https://doi.org/10.1039/dt9760002165

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Reduction-oxidation properties of organotransition-metal complexes. Part 12. Formation of carbon–carbon bonds via the oxidative dimerisation of [Fe(CO)3(η4-C8H8)] and the reduction of [Fe2(CO)6(η5:η′5-C16H16)]2+; X-ray crystal structures of [Fe2(CO)4{P(OPh)3}2(η5:η′5-C16H16)][PF6]2and [Fe(CO)3(η4-C16H16)]

Autor: Peter Woodward, Robert F. D. Stansfield, Susan M. Whiting, Raymond L. Kelly, Neil G. Connelly, Rona M. Mills, Maureen D. Kitchen, Mark W. Whiteley

Publikováno v: J. Chem. Soc., Dalton Trans.. :1317-1326

The complexes [Fe(CO)3 –nLn(η4-cot)][1: cot = cyclo-octatetraene; n= 0–3, L = P(OMe)3; n= 1, L = P(NMe2)3, PPh3, P(OCH2)3CMe, or P(OPh)3] undergo chemically irreversible one-electron oxidation in CH2Cl2 at a platinum electrode. Chemical generati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fcad14ffdf378a4e16b619f4d26920df
https://doi.org/10.1039/dt9810001317

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Reduction–oxidation properties of organotransition-metal complexes. Part 5. The one-electron oxidation of tricarbonyl(η-cyclopentadienyl)-manganese derivatives and the reactivity of the resulting radical cations

Autor: Neil G. Connelly, Maureen D. Kitchen

Publikováno v: J. Chem. Soc., Dalton Trans.. :931-937

Cyclic-voltammetric studies in CH2Cl2 have shown that [Mn(η-C5H5–nMen)(CO)3–xLx][n= 0, 1, or 5, x= 1, L = phosphine or phosphite (1); n= 0 or 1, x= 2, L =½dppe (dppe = Ph2PCH2CH2PPh2), PPh3, or PMePh2] each undergo a reversible one-electron oxi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::92015e616635ae63c5c7acec54f7e8e4
https://doi.org/10.1039/dt9770000931

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Reduction–oxidation properties of organotransition-metal complexes. Part 9. Silver(I) adducts of cyclic polyeneone complexes, the X-ray crystal structure of [{Fe(CO)3[η5-C5Ph4OAg(OH2)]}2][PF6]2, and comments on the use of the silver(I) ion as a one-electron oxidant

Autor: Maureen D. Kitchen, Peter Woodward, Barbara A. Kelly, Paul K. Baker, Neil G. Connelly, Karen Broadley

Publikováno v: J. Chem. Soc., Dalton Trans.. :1710-1715

The tetraphenylcyclopentadienone complexes [M(CO)2L(η4-C5Ph4O)][1; M = Fe, L = CO, PPh3, or P(OMe)3; M = Ru, L = CO] and [Rh(η5-C5H5)(η4-C5Ph4O)](2) react with Ag[PF6] to give dimeric oxygen-bonded silver adducts [{M(CO)2L(η5-C5Ph4OAg)}2][PF6]2(3

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8d3b8edf93cc0a0fb34f3709c318a546
https://doi.org/10.1039/dt9800001710

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Reduction—oxidation properties of organotransition metal complexes VII. The dimerisation of coordinated cyclooctatetraene via silver(I) oxidation, and the x-ray crystal structure of [Fe2(CO)4{P(OPh)3}2(η5,η′5-C16H16)][PF6]2

Autor: Susan M. Whiting, Neil G. Connelly, Maureen D. Kitchen, Robert F. D. Stansfield, Peter Woodward

Publikováno v: Journal of Organometallic Chemistry. 155:C34-C36

The complex [Fe(CO) 2 L(η 4 -C 8 H 8 )] (L = CO, PPh 3 , or P(OPh) 3 ) reacts with [( p -BrC 6 H 4 ) 3 N] [PF 6 ] or with AgPF 6 to give, via one-electron oxidation followed by dimerisation, [Fe 2 (CO) 4 L 2 (η 5 ,η′ 5 -C 16 H 16 )] [PF 6 ] 2 ,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cf1cf429e2536e34465258a995a5c11d
https://doi.org/10.1016/s0022-328x(00)93301-1

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ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION-METAL COMPLEXES. PART 5. THE ONE-ELECTRON OXIDATION OF TRICARBONYL(η-CYCLOPENTADIENYL)MANGANESE DERIVATIVES AND THE REACTIVITY OF THE RESULTING RADICAL CATIONS

Autor: Neil G. Connelly, Maureen D. Kitchen

Publikováno v: Chemischer Informationsdienst. 8

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dbebe54ff1470348a998185f6b58dea5
https://doi.org/10.1002/chin.197729300

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ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 9. SILVER(I) ADDUCTS OF CYCLIC POLYENEONE COMPLEXES, THE X-RAY CRYSTAL STRUCTURE OF ((FE(CO)3(η5-C5PH4OAG(OH2)))2)(PF6)2, AND COMMENTS ON THE USE OF THE SILVER(I

Autor: Paul K. Baker, Neil G. Connelly, Peter Woodward, Barbara A. Kelly, K. Broadley, Maureen D. Kitchen

Publikováno v: Chemischer Informationsdienst. 11

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::17c322cd4d55dd82e52be8c423c35b3e
https://doi.org/10.1002/chin.198049071

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