Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Matthias W, Esterhuysen"'
Publikováno v:
Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1534-m1534 (2008)
The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle o
Externí odkaz:
https://doaj.org/article/b63af3455770468c8bedaee86afd577e
Publikováno v:
Inorganica Chimica Acta. 358:4217-4228
Reaction of [(CO) 5 WC(O)Ph]Li or [(CO) 5 WC(O)Ph]NBu 4 with Ph 3 PAuCl affords acyl complexes of gold. In the latter conversion, both the crystalline products [(CO) 5 WCl]NBu 4 ( 2 ) and Ph 3 PAuC(O)Ph ( 3 ) have been isolated and fully characterise
Publikováno v:
European Journal of Inorganic Chemistry. 2003:3861-3869
Efficient syntheses and isolation procedures of two closely related benzoyl−W(CO)5 compounds, [{Li(diglyme)}{Ph(O)CW(CO)5}] (1) and [Li(diglyme)2][(μ2-H){Ph(O)CW(CO)5}2] (2) are reported. The empirical formulae of 1 and 2 differ only in that the l
Publikováno v:
Inorganica Chimica Acta. 348:205-211
The sodium heptamolybdate compound (1) was crystallized at pH ∼6.9 from an acidified sodium molybdate solution. X-ray structural analysis shows a novel empirical formula of Na7[Mo7O24]OH·21H2O for this compound in which a complex network of ion–
Autor:
Helgard G. Raubenheimer, Alexey Y. Timoshkin, Matthias W. Esterhuysen, Gernot Frenking, Yu Chen
Publikováno v:
Organometallics. 21:3173-3181
The addition of the Ph3PAu+ electrophile to deprotonated Fischer-type alkoxy(methyl)carbene complexes of pentacarbonyl group 6 metals leads to the formation of novel vinyl ether complexes of gold c...
Autor:
Gert J. Kruger, Robert Brüll, Helgard G. Raubenheimer, Matthias W. Esterhuysen, Catharine Esterhuysen
Publikováno v:
Journal of Organometallic Chemistry. 619:164-178
Reaction of trans -[PdCl(Ph)(PPh 3 ) 2 ] with the thallium salts R–X–(CH 2 ) n –COOTl ( n =1, X=S, R=Me, Et, i -Pr, t -Bu, Ph; n =1, X=Se, R=Me, Ph; n =2, X=S, R=Et, Ph) yields the compounds trans -[Pd(OOC–(CH 2 ) n –X–R–κ 1 - O )Ph(PP
Autor:
Gernot Frenking, Matthias W. Esterhuysen, Catharine Esterhuysen, Ulrike E. I. Horvath, Alexey Y. Timoshkin, Helgard G. Raubenheimer
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (38)
Deprotonated Fischer-type aminocarbene complexes, (CO)5M=C(NR2)CH3 (M = Cr or W; R = Me or propyl), react with Ph3PAu+ by metal group substitution - (CO)5M for Ph3PAu+--and attachment of the extricated M(CO)5 to the deprotonated methyl group. (The pr
Autor:
Wolfgang H, Meyer, Maggel, Deetlefs, Michael, Pohlmann, Roland, Scholz, Matthias W, Esterhuysen, Gerrit R, Julius, Helgard G, Raubenheimer
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (3)
A series of palladium, platinum and manganese di(organo)carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms are separat
Autor:
Julia Even, Helgard G. Raubenheimer, Matthias W. Esterhuysen, Catharine Esterhuysen, Ulrike E. I. Horvath, Elzet Stander
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 62:m1625-m1626
The title compound, [Cr(C5H10S)(CO)5], comprises a methyl(n-propylsulfanyl)carbene ligand coordinated to a pentacarbonylchromium fragment, with the Cr atom in an octahedral coordination.
Publikováno v:
Acta Crystallographica Section E: Structure Reports
The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twist