Výsledky vyhledávání - "Matthias Manger"

A new synthetic route to ligands of the general composition R2PCH2ER′2 (E = P, As) and some rhodium complexes derived thereof

Autor: Helmut Werner, Matthias Manger, Justin Wolf, Birgit Weberndörfer, David A. Vicic, Guido Fries, Dietmar Barth, William D. Jones, Ulrich Schmidt

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1867-1876

Symmetrical and unsymmetrical bis(phosphino)methanes R2PCH2PR′2 (8–16) as well as the arsino(phosphino) analogues R′2AsCH2PR2 (21–25) with bulky alkyl, cycloalkyl or aryl groups R and R′ were prepared from the stannylated phosphines R2PCH2S

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::aedf4cb5d326faebfcf2b4488d060747
https://doi.org/10.1039/a902139f

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Two dinuclear rhodium complexes with a non-A-frame and a distorted A-frame skeleton and two iPr2PCH2PiPr2 molecules as bridging ligands

Autor: Matthias Laubender, Markus Teichert, Dietmar Stalke, Matthias Manger, Helmut Werner

Publikováno v: Journal of Organometallic Chemistry. 569:189-194

The π-allyl(carbonyl)rhodium(I) complex [Rh(η3-C3H5)(CO)(κ2-iPr2PCH2PiPr2)] (2), which was obtained from [Rh(η3-C3H5)(κ2-iPr2PCH2PiPr2)] (1) and CO, reacted with H2 at room temperature to give the dinuclear hydrido compound [{Rh(CO)(μ-H)(μ-iPr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e41d9743290a9a7fbaf9fbd5ce110a4e
https://doi.org/10.1016/s0022-328x(98)00787-6

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Syntheses, Molecular Structures, and Reactivities of (π-Allyl)rhodium(I) Complexes Containing Bulky Bis(phosphino)methanes R‘2PCH2PiPr2 as Ligands

Autor: Justin Wolf, Helmut Werner, Markus Teichert, Matthias Manger, Dietmar Stalke

Publikováno v: Organometallics. 17:3210-3221

The π-allyl complexes [Rh(η3-2-RC3H4)(κ2-R‘2PCH2PiPr2)] (R = H, Me; R‘ = iPr, Cy, Ph) (2−7) were prepared from [RhCl(η4-C8H12)]2, 2-RC3H4MgX, and R‘2PCH2PiPr2 via [Rh(η3-2-RC3H4)(η4-C8H12)] as the intermediate. Reaction of 2−4 (R = H)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bc13122664b6eab25b7531b0dc861136
https://doi.org/10.1021/om980062m

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Organometallic Rhodium Complexes Containing Peralkylated Arsino(phosphino)methanes as Ligands

Autor: Ulrich Schmidt, Helmut Werner, Matthias Manger, Matthias Laubender, Birgit Weberndörfer

Publikováno v: Organometallics. 17:2619-2627

The peralkylated arsino(phosphino)methanes R2AsCH2PR2 (R = iPr, Cy) reacted with [{(η4-C8H12)RhCl}2] by cleavage of the chloro bridges to give the mononuclear compounds [RhCl(η4-C8H12)(κ-P-R2PCH2As...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9380bf60ff0f2bce312451b7621f6050
https://doi.org/10.1021/om971085o

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Preparation, molecular structure and reactivity of mono- and di-nuclear sulfonato rhodium(I) complexes

Autor: Christine Hahn, Bettina Windmüller, Matthias Laubender, Frank Kukla, Michael Schneider, Matthias Manger, Marco Bosch, Helmut Werner, Birgit Weberndörfer

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :3549-3558

The reaction of [Rh(η3-C3H5)(PPri3)2] 1 or [Rh(η3-CH2Ph)(PPri3)2] 2 with an equimolar amount of RSO3H (R = Me, p-tolyl, CF3, F, Camph) led to the formation of the monomeric sulfonatorhodium(I) complexes [Rh{η2-O2S(O)R}(PPri3)2] 3–7 in excellent

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d6c55b6259153ae512312a775cf569c4
https://doi.org/10.1039/a805900d

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The First Peralkylated Phosphino(stibino)methanes and Their Organometallic Rhodium Complexes

Autor: Helmut Werner, Dietmar Stalke, Matthias Manger, Matthias Laubender, Markus Teichert, Justin Wolf

Publikováno v: Chemistry - A European Journal. 3:1442-1450

The first representatives of phosphino(stibino)methanes R2PCH2Sb-R′2 (3–5) with bulky alkyl or cycloalkyl groups R and R′ were prepared in two steps from Ph3SnCH2I via the isolated stannylated phosphanes Ph3SnCH2PR2 (1, 2) as intermediates. X-r

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3ed9038ed985750a37567134ecd4dd33
https://doi.org/10.1002/chem.19970030910

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Unusual Dinuclear Hydridorhodium(III) Complexes Containing Bulky Phosphanyl(stibanyl)methanes as Chelating Ligands

Autor: Matthias Manger, Olaf Gevert, Helmut Werner

Publikováno v: Chemische Berichte. 130:1529-1531

The mononuclear starting materials [Rh(η4-C8H12)(k2-P,Sb-iPr2PCH2SbR2)]PF6 (la, b) react with CF3CO2H in the presence of H2 to give the dinuclear hydridorhodium(II1) complexes [{RhH(k2-P,Sb-iPr2PCH2SbR2)]PF6 (2a, b) in almost quantitative yield. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b9a213db6fa9a6c0a881e85c138b8a4a
https://doi.org/10.1002/cber.19971301028

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Vinylidene transition-metal complexes. 37. Novel Synthetic Route to Vinylidenerhodium(I) and -iridium(I) Complexes Using Vinyl Chlorides as Substrates

Autor: Raimund W. Lass, Justin Wolf, Helmut Werner, Matthias Manger

Publikováno v: Organometallics. 14:2649-2651

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::93f895dc197032c672f4976dbcede540
https://doi.org/10.1021/om00006a010

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