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pro vyhledávání: '"Matthias Czakler"'
Publikováno v:
Monatshefte für Chemie - Chemical Monthly. 151:1697-1703
Abstract The organically modified titanium alkoxides Ti2(Oi-Pr)4(OOCCMe2O)2(i-PrOH)2 and Ti4(Oi-Pr)4(SA)6 were obtained from the reaction of Ti(Oi-Pr)4 with 2-hydroxy-isobutyric acid and salicyladoxime (SA-H2), respectively. Reaction of 1,3-dibenzoyl
Publikováno v:
New Journal of Chemistry. 42:12098-12103
Ti6O6(OiPr)2(OOCR′)10 (R′ = C4H7, Et) and Ti6O3(OiPr)14(OOC–CHCH–COO)2 represent new structure types of carboxylate-substituted clusters with a Ti6Ox core (x = 3–6). They complement the already known six structure types and thus allow concl
Autor:
Matthias Czakler, Ulrich S. Schubert
Publikováno v:
Inorganica Chimica Acta. 471:567-569
Ti3O(OiPr)6(OOC-adamantyl)4 and Ti3O2(OiPr)3(OOCCPh3)5 were obtained from the reaction of Ti(OiPr)4 with adamantylcarboxylic or triphenylacetic acid, respectively. The structures of both are based on a central Ti3O unit, which is substituted by diffe
Autor:
Matthias Czakler, Ulrich S. Schubert
Publikováno v:
Monatshefte Fur Chemie
The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. T
Autor:
Matthias Czakler, Michael Puchberger, Ulrich S. Schubert, Johannes Kreutzer, Ernst Pittenauer
Publikováno v:
European Journal of Inorganic Chemistry
Reaction of [Ti4Zr4O6(OBu)4(OMc)16] (OMc = methacrylate) with acetylacetone (acacH) resulted in dissection of the cluster and formation of [Ti(OBu)2(acac)2] and the smaller cluster [Ti2Zr4O4(OMc)16]. In contrast, the same reaction with [Zr6O4(OH)4(OO
Publikováno v:
Monatshefte für Chemie - Chemical Monthly. 146:897-902
When Ti(OiPr)4 was reacted with increasing proportions of methacrylic acid (McOH), the compounds Ti2(OiPr)6(OMc)2(iPrOH), Ti6O4(OiPr)8(OMc)8, Ti9O8(OiPr)4(OMc)16, and Ti8O8(OMc)16 were obtained in sequence. This allowed conclusions on the relative ra
Publikováno v:
European Journal of Inorganic Chemistry
The mixed-metal oxo clusters LnTi4O3(OiPr)2(OMc)11 (Ln = La, Ce; OMc = methacrylate), Ln2Ti6O6(OMc)18(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln2Ti4O4(OMc)14(HOMc)2 (Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding la
Publikováno v:
The Journal of Physical Chemistry. C, Nanomaterials and Interfaces
Recently we published the synthesis of new hybrid materials, ionic silica nanoparticles networks (ISNN), made of silica nanoparticles covalently connected by organic bridging ligands containing imidazolium units owing to a “click-chemistry-like”
Publikováno v:
Monatshefte Fur Chemie
When Ti(OiPr)4 was reacted with increasing proportions of methacrylic acid (McOH), the compounds Ti2(OiPr)6(OMc)2(iPrOH), Ti6O4(OiPr)8(OMc)8, Ti9O8(OiPr)4(OMc)16, and Ti8O8(OMc)16 were obtained in sequence. This allowed conclusions on the relative ra
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 20(2)
Mixed-metal clusters have been obtained from the reaction of titanium alkoxides with either strontium or lead acetate and methacrylic acid. The structures of the clusters are derived from the metallacycle Ti8 O8 (methacrylate)16 . The Sr and Pb atoms