Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Matthew W. Small"'
Autor:
Matthew W. Small, Annika Elsen, Anatoly I. Frenkel, Ralph G. Nuzzo, Jeremy G. Smith, Yuanyuan Li, Ulrich Jung, Eric A. Stach
Publikováno v:
ACS Catalysis. 5:1539-1551
There exists an emerging opportunity, engendered by advances made in experimental methods of research, to address long-standing questions about the nature of the molecular mechanisms that are operative in important heterogeneous catalytic processes,
Autor:
Matthew W. Small, John J. Rehr, Joshua J. Kas, Anatoly I. Frenkel, Kristina O. Kvashnina, Moniek Tromp, Ralph G. Nuzzo
Publikováno v:
ChemPhysChem. 15:1569-1572
Determination of the factors that affect the d-band center of catalysts is required to explain their catalytic properties. Resonant inelastic X-ray scattering (RIXS) enables direct imaging of electronic transitions in the d-band of Pt catalysts in re
Autor:
Matthew W. Small, Kristina O. Kvashnina, Anatoly I. Frenkel, Ralph G. Nuzzo, Jeremy G. Smith, Moniek Tromp
Publikováno v:
The Journal of Physical Chemistry C. 117:23286-23294
The electronic and atomic structural properties of nanoscale metal catalysts exhibit complex influences with origins related to particle size, metal–support, and metal–adsorbate interactions. The experimental investigations of these factors, as w
Publikováno v:
ACS Nano. 6:5583-5595
We describe the results of an X-ray absorption spectroscopy (XAS) study of adsorbate and temperature-dependent alterations of the atomic level structure of a prototypical, noble metal hydrogenation and reforming catalyst: ∼1.0 nm Pt clusters suppor
Autor:
Joo Kang, Matthew W. Small, Ralph G. Nuzzo, Sergio I. Sanchez, Laurent D. Menard, Anatoly I. Frenkel
Publikováno v:
Journal of the American Chemical Society. 133:3582-3591
This study describes a prototypical, bimetallic heterogeneous catalyst: compositionally well-defined Ir-Pt nanoclusters with sizes in the range of 1-2 nm supported on γ-Al(2)O(3). Deposition of the molecular bimetallic cluster [Ir(3)Pt(3)(μ-CO)(3)(
Autor:
Sergio I. Sanchez, Jianguo Wen, Matthew W. Small, Shankar Sivaramakrishnan, Ralph G. Nuzzo, Jian-Min Zuo
Publikováno v:
Analytical Chemistry. 82:2599-2607
Analytical electron microscopy--empowered by advances in electron optics and detectors--is poised to radically transform our understanding of the complex phenomena arising from atomic and electronic structure in materials chemistry. (To listen to a p
Publikováno v:
Synchrotron Radiation News. 22:6-11
Supported metal catalysts enable the production of essentially all forms of liquid hydrocarbon fuels as well as facilitate a multitude of other industrial processes. Catalytic behavior is influenced by a plethora of competing factors of which the mos
Autor:
Matthew W. Small, Ralph G. Nuzzo, Anatoly I. Frenkel, Eric A. Stach, Yuanyuan Li, Jeremy G. Smith, Ulrich Jung, Annika Elsen
Publikováno v:
ChemInform. 46
There exists an emerging opportunity, engendered by advances made in experimental methods of research, to address long-standing questions about the nature of the molecular mechanisms that are operative in important heterogeneous catalytic processes,
Autor:
Matthew W. Small, Michael W. Cason, Judith C. Yang, John J. Rehr, Eric A. Stach, Anatoly I. Frenkel, Fernando D. Vila, Annika Elsen, Ralph G. Nuzzo, Ulrich Jung
Publikováno v:
ChemInform. 45
This review article takes a new look at the problem of characterization of structural properties and reaction dynamics of supported metal catalysts. Such catalysts exhibit an inherent complexity, particularly due to interactions with the support and
Autor:
Anatoly I. Frenkel, Andrew A. Gewirth, Matthew W. Small, Evan M. Erickson, David J. Wetzel, Diya Li, Ralph G. Nuzzo, Thao T. H. Hoang, Muhammed Enes Oruc, Michael W. Cason
Publikováno v:
Analytical chemistry. 86(16)
Microcantilever stress measurements are examined to contrast and compare their attributes with those from in situ X-ray absorption spectroscopy to elucidate bonding dynamics during the oxygen reduction reaction (ORR) on a Pt catalyst. The present wor