Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Matthew R. Elsby"'
Autor:
Matthew R. Elsby, R. Tom Baker
Publikováno v:
Accounts of Chemical Research. 56:798-809
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::89c3abd90458858cd99f6fd40ca5cb69
https://doi.org/10.1021/acs.accounts.2c00798
https://doi.org/10.1021/acs.accounts.2c00798
Publikováno v:
Chemical Science. 13:12550-12559
The role of a phosphine-free SNS-pincer ligand in metal–ligand cooperative hydroboration catalysis was investigated. The bifunctional thiolate donor and spin-state change to high-spin Mn are crucial to accessing low-energy activation barriers.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9f14d7793fd0e4e2e35fe8f89cc2737e
https://doi.org/10.1039/d2sc04339d
https://doi.org/10.1039/d2sc04339d
Autor:
Matthew R. Espinosa, Mehmed Z. Ertem, Mariam Barakat, Quinton J. Bruch, Anthony P. Deziel, Matthew R. Elsby, Faraj Hasanayn, Nilay Hazari, Alexander J. M. Miller, Matthew V. Pecoraro, Allison M. Smith, Nicholas E. Smith
Publikováno v:
Journal of the American Chemical Society. 144(39)
The kinetics of hydride transfer from Re(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::10bf784a5d8683215aa9c674729c7b18
https://pubmed.ncbi.nlm.nih.gov/36130605
https://pubmed.ncbi.nlm.nih.gov/36130605
Publikováno v:
ACS Catalysis. 11:9043-9051
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a96a310c7df578d80ae84fdf47ededc5
https://doi.org/10.1021/acscatal.1c02238
https://doi.org/10.1021/acscatal.1c02238
Publikováno v:
Chemical science. 13(42)
The role of S-donors in ligand-assisted catalysis using first-row metals has not been broadly investigated. Herein is described a combined experimental and computational mechanistic study of the dihydroboration of nitriles with pinacolborane (HBpin)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::11e84a3764c9bb3094016b3e307eb271
https://pubmed.ncbi.nlm.nih.gov/36382284
https://pubmed.ncbi.nlm.nih.gov/36382284
Publikováno v:
Dalton Transactions
Dalton Transactions, 2021, 50 (41), pp.14542-14546. ⟨10.1039/D1DT02637B⟩
Dalton Transactions, 2021, 50 (41), pp.14542-14546. ⟨10.1039/D1DT02637B⟩
The bifunctional reactivity of three metal SNS (bis)amido complexes was computationally assessed by comparing the nucleophilicity of the M–Namido donor (Mn, Fe, Co). Hirshfeld charges identified the Mn–Namido donor as most nucleophilic and Fe as
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d657352f9adb1ae37609aba20d8ea2a
https://doi.org/10.1039/d1dt02637b
https://doi.org/10.1039/d1dt02637b
Publikováno v:
Organometallics. 38:3844-3851
The synthesis, structure, and reactivity of an electron-rich FeII thioether-imine-thiolate complex, [Fe(SMeNS)(PMe3)3](OTf) (1-SNS), prepared by reaction of Fe(OTf)2(PMe3)4 with the SMeNHS ligand i...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5c1c274c0e5e7b2083abbc4145147e82
https://doi.org/10.1021/acs.organomet.9b00524
https://doi.org/10.1021/acs.organomet.9b00524
Publikováno v:
Organometallics. 38:436-450
A series of Ni(0) compounds supported by electronically similar N-heterocyclic carbene (NHC) ancillary ligands with a range of %Vbur were used as catalysts for aryl C–H bond silylation, germylation, and stannylation. The NHC steric bulk strongly in
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ae589bba9a82311078c0c6f240ef256e
https://doi.org/10.1021/acs.organomet.8b00786
https://doi.org/10.1021/acs.organomet.8b00786
Autor:
Matthew R. Elsby, R. Tom Baker
Publikováno v:
Chemical Society reviews. 49(24)
The use of metal-ligand cooperation (MLC) by transition metal bifunctional catalysts has emerged at the forefront of homogeneous catalysis science. Specially designed ligands can serve a Lewis base or Lewis acid function, as an aromatization/dearomat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2bb304b88233e86796e1a9089a03e4fc
https://pubmed.ncbi.nlm.nih.gov/33164012
https://pubmed.ncbi.nlm.nih.gov/33164012
Autor:
R. Tom Baker, Matthew R. Elsby
Publikováno v:
Chemical communications (Cambridge, England). 55(90)
Two new NHC-Cu(i)-[κ2-SNS] complexes were synthesized to directly compare the bifunctional catalytic activity of a hard amido vs. a soft thiolate donor. The Cu thiolate complex catalyzed ketone hydroboration but not hydrosilylation, while the Cu ami
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::816abc29fd074e34870d5292b7feaeca
https://pubmed.ncbi.nlm.nih.gov/31656960
https://pubmed.ncbi.nlm.nih.gov/31656960