Zobrazeno 1 - 10 of 101 pro vyhledávání: '"Matthew P, Shores"'
1
Influence of Coordinated Triflate Anions on the Solution Magnetic Properties of a Neutral Iron(II) Complex
Autor: Matthew P. Shores, Brooke N. Livesay
Publikováno v: Inorganic Chemistry. 60:15445-15455
In an effort to probe the impacts of speciation on spin-state switching, the synthesis and unique solution-phase magnetic properties of [((TIPSC≡C)3tren)Fe(OTf)2] (1) are described. Analysis of the single-crystal X-ray diffraction data shows that t
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::95b90be5fa720eb5e980db4671de0937
https://doi.org/10.1021/acs.inorgchem.1c02112
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2
A systematic study of the influence of ligand field on the slow magnetic dynamics of Co(ii)-diimine compounds
Autor: Indrani Bhowmick, Matthew P. Shores, Brian S. Newell
Publikováno v: Dalton Transactions. 50:10737-10748
Herein we report heteroleptic Co(II) diimine complexes [Co(H2bip)2Cl2] (1), [Co(H2bip)2Br2] (2), [Co(H2bip)3]Br2·1MeOH (3) and [Co(H2bip)2(Me2bpy)]Br2·(MeCN)0.5·(H2O)0.25 (4) (H2bip = 2,2′-bi-1,4,5,6-tetrahydropyrimidine, bpy = 2,2′-dipyridyl,
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::246e8a79ea0e101d26279eb0cf191f14
https://doi.org/10.1039/d0dt01597k
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3
Long-Lived Mixed 2MLCT/MC States in Antiferromagnetically Coupled d3 Vanadium(II) Bipyridine and Phenanthroline Complexes
Autor: Ryan D. Dill, Anthony K. Rappé, Samuel G. Shepard, Matthew P. Shores, Niels H. Damrauer, Romeo I. Portillo
Publikováno v: Inorganic Chemistry. 59:14706-14715
Exploration of [V(bpy)3]2+ and [V(phen)3]2+ (bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline) using electronic spectroscopy reveals an ultrafast excited-state decay process and implicates a pair ...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::67f7c2ecc2af940f75a6c28bed4c83d1
https://doi.org/10.1021/acs.inorgchem.0c01950
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4
Understanding the Origin of One- or Two-Step Valence Tautomeric Transitions in Bis(dioxolene)-Bridged Dinuclear Cobalt Complexes
Autor: Matthew P. Shores, Robert W. Gable, Jett T Janetzki, Brooke N. Livesay, Alyona A. Starikova, Gemma K. Gransbury, Colette Boskovic, Moya A. Hay
Publikováno v: Journal of the American Chemical Society. 142:10692-10704
Valence tautomerism (VT) involves a reversible stimulated intramolecular electron transfer between a redox-active ligand and redox-active metal. Bis(dioxolene)-bridged dinuclear cobalt compounds provide an avenue toward controlled two-step VT interco
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd0e9e0f2baff17b5ac04091546dfe1c
https://doi.org/10.1021/jacs.0c01073
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5
Electronic Structures of Cr(III) and V(II) Polypyridyl Systems: Undertones in an Isoelectronic Analogy
Autor: Matthew P. Shores, Michael P. Nguyen, Anthony K. Rappé, Romeo I. Portillo, Collette M. Nite, Justin P. Joyce, Jacob M. Nite
Publikováno v: Inorganic chemistry. 60(17)
A recently reported description of the photophysical properties of V2+ polypyridyl systems has highlighted several distinctions between isoelectronic, d3, Cr3+, and V2+ tris-homoleptic polypyridyl complexes of 2,2'-bipyridine (bpy) and 1,10-phenanthr
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e569ed1d6f30bfb9566647754122e24a
https://pubmed.ncbi.nlm.nih.gov/34382400
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6
Systematic Investigation of the Molecular and Electronic Structure of Thorium and Uranium Phosphorus and Arsenic Complexes
Autor: Justin R. Walensky, O. Jonathan Fajen, Matthew P. Shores, Steven P. Kelley, Thomas L. Morrison, Andrew Kerridge, Xhensila Xhani, Thomas Malcomson, Michael L. Tarlton
In continuing to examine the interaction of actinide-ligand bonds with soft donor ligands, a comparative investigation with phosphorus and arsenic was conducted. A reaction of (C5Me5)2AnMe2, An = Th, U, with 2 equiv of H2AsMes, Mes = 2,4,6-Me3C6H2, f
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9c32cc875cce3c307ddffd2a64b95185
https://doi.org/10.1021/acs.inorgchem.1c01256
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7
Magnetization Slow Dynamics in Ferrocenium Complexes
Autor: Mei Ding, Mathieu Rouzières, Jeremy M. Smith, Martín Amoza, Joshua Telser, Wesley A. Hoffert, Tarik J. Ozumerzifon, David L. Tierney, Matthew P. Shores, Eliseo Ruiz, Anne K. Hickey, Maren Pink, Rodolphe Clérac
Publikováno v: Dipòsit Digital de la UB
Universidad de Barcelona
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2019, 25 (45), pp.10625-10632. ⟨10.1002/chem.201900799⟩
International audience; The single-molecule magnet (SMM) properties of a series of ferrocenium complexes, [Fe(h5-C5R5)2]+ (R=Me, Bn), are reported. In the presence of an applied dc field, the slow dynamics of the magnetization in [Fe(h5-C5Me5)2]BArF
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9b9b644c529007f367559fbd14e34e1
https://doi.org/10.1002/chem.201900799
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8
Heterobimetallic {PtMn} and {PtFe} lantern complexes with exceptionally long metallophilic contacts
Autor: Matthew P. Shores, Romeo I. Portillo, Linda A. Zuckerman, Linda H. Doerrer, Stephanie A. Beach, Arnold L. Rheingold
Publikováno v: Inorganica Chimica Acta. 493:81-90
A new series of heterobimetallic lantern complexes, [PtM(SAc)4(pySMe)] (M = Mn (1), Fe (2), Co (3), Ni (4), Zn (5)), as well as additions to the previously reported series, [PtM(SAc)4(pyNH2)] (M = Mn (6), Fe (7)), have been synthesized and thoroughly
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e36bb28c63ee3c58380431dcbbd99ad3
https://doi.org/10.1016/j.ica.2019.04.054
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9
Evidence for Reagent-Induced Spin-State Switching in Tripodal Fe(II) Iminopyridine Complexes
Autor: Justin P. Joyce, Robert F. Higgins, Tarik J. Ozumerzifon, Jacek L. Kolanowski, Matthew P. Shores, Anthony K. Rappé
Publikováno v: Inorganic Chemistry. 58:7785-7793
We present evidence of a spin-state change that accompanies desilylation reactions performed on two related Fe(II) iminopyridine coordination complexes. To probe these systems, we performed titrations with CsF in solution and analyzed the speciation
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4ab658882141ce27cb7ae31f63f227a8
https://doi.org/10.1021/acs.inorgchem.9b00340
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10
Investigation of the Electronic Structure of Aryl-Bridged Dinuclear U(III) and U(IV) Compounds
Autor: Robert F. Higgins, Paul G. Wenthold, Christopher L. Clark, Matthew P. Shores, Robert J. Ward, Matthias Zeller, John J. Kiernicki, James C. Langford, Justin R. Walensky, Sean N. Natoli, Caleb J. Tatebe, Suzanne C. Bart
Publikováno v: Organometallics. 38:1031-1040
A family of dinuclear bis(Tp*) (Tp* = hydrotris(3,5-dimethylpyrazolyl)borate) uranium compounds with conjugated organic linkers was synthesized to explore possible electronic communication between ...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::954370e3a46bc27312a6956c61329c33
https://doi.org/10.1021/acs.organomet.8b00794
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