Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Matthew John Byrnes"'
Autor:
William Roy Jackson, Andrea J. Robinson, Clint Peter Woodward, Andrew Merrick Hilton, Matthew John Byrnes
Publikováno v:
Green Chem.. 14:81-84
A quaternary ammonium Hoveyda-Grubbs olefin metathesis pre-catalyst has been reversibly immobilized on sulphonic acid-functionalised silica-coated iron oxide magnetic particles to affect ring closing metathesis with easy removal, reuse and regenerati
Publikováno v:
Dalton Trans.. :1677-1686
Two equivalents of Ph2PCCR (R = H, Me, Ph) react with thf solutions of cis-[Ru(acac)2(η2-alkene)2] (acac = acetylacetonato; alkene = C2H4, 1; C8H14, 2) at room temperature to yield the orange, air-stable compounds trans-[Ru(acac)2(Ph2PCCR)2] (R = H,
Publikováno v:
Organometallics. 24:4437-4450
Reactions between [HIPTN3N]Mo(N2) and ethylene, acetylene, or CO yield Mo(η2-C2H4), Mo(η2-C2H2), and Mo(CO), respectively ([HIPTN3N]3- = [3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2]3N3-; HIPT = hexaisopropylterphenyl; [HIPTN3N]Mo = Mo). All are paramagnetic
Autor:
Matthew John Byrnes, Alison J. Edwards, Guandolina Chung, Martin A. Bennett, Anthony C. Willis
Publikováno v:
Inorganica Chimica Acta. 358:1692-1708
Reaction of cis-[Ru(acac)2(η2-C8H14)2] (1) (acac = acetylacetonato) with two equivalents of PiPr3 in THF at −25 °C gives trans-[Ru(acac)2(PiPr3)2], trans-3, which rapidly isomerizes to cis-3 at room temperature. The poorly soluble complex [Ru(aca
Publikováno v:
Journal of Organometallic Chemistry. 689:4463-4474
Reduction of [Ru(acac) 3 ] with zinc in THF/H 2 O provides a range of coordination and organometallic complexes containing Ru II (acac) 2 , whose chemistry is reviewed. Most of these compounds, including those containing alkenes, undergo reversible o
Autor:
Matthew John Byrnes, Judith A Gallucci, Nathan J. Patmore, Robin J. H. Clark, Malcolm H. Chisholm, Christopher M. Hadad
Publikováno v:
Inorganic Chemistry. 43:6334-6344
A series of compounds of the form [M(2)L(4)] and [[((t)()BuCO(2))(3)M(2)](2)(mu-L')] have been made where M = Mo or W, L = a thienyl, bithienyl, or terthienyl carboxylate, and L' = a corresponding thienyl dicarboxylate. The electronic absorption spec
Publikováno v:
Macromolecules. 37:4139-4145
Oligoether carbonates R(PO)nOCO2(PO)nR, where R = Me, Et, or H, PO = propylene oxide ring-opened unit, and n = 1, 2, 3, 4, ∼10, and ∼30, have been prepared and characterized by ESI/MS or MALDI/MS a...
Publikováno v:
Organometallics. 22:1018-1028
Zinc dust reduction of tris(acetylacetonato)ruthenium(III), [Ru(acac)3], in hot aqueous THF in the presence of ethene gives cis-[Ru(acac)2(η2-C2H4)2] (5), isolated as an orange solid in ca. 60% yield. A single-crystal X-ray crystallographic study sh
Publikováno v:
Organometallics. 21:2240-2247
Aromatic hydrocarbon solutions of [W 2 (O 2 C t Bu) 4 ] react with alkynes RC≡CR' to give adducts of the formula [W 2 (κ 2 -O 2 C t Bu) 4 (μ-RCCR') 2 ], where R = R' = Me, Et, Ph and R = Me, R' = Ph, as orange to purple air-stable,hydrocarbon-sol
Publikováno v:
Journal of Organometallic Chemistry. 571:139-144
The endo-tetramethyl-o-xylylene complexes M(η6-C6Me6){η4-o-C6Me4(CH2)2} (M=Ru (endo-1), Os (endo-2)) isomerize to their exo-isomers on heating in the solid state at 400°C for 5 min. The osmium compound exo-2 forms a 1:1 adduct with PMe3, Os(PMe3)(