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pro vyhledávání: '"Matthew J. G. Sinclair"'
The well-defined Pd(I) metalloradical [Pd(PtBu3)2]+ reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PtBu3)(μ-I)]2 and phosphonium salts. Pd(II) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c631150ca82a0805214049e442925dde
The synthesis of an unusual T-shaped alkylpalladium(II) complex featuring a cyclometalated tri-tert-butylphosphineoxide ligand by oxidation of the corresponding cyclometalated tri-tert-butylphosphine complex with PhIO is reported. We speculate that t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b97f26366177b072f4ba8a88638f094a
http://wrap.warwick.ac.uk/140390/7/WRAP-Oxidative-ring-expansion-low-coordinate-palladacyclesynthesis-Chaplin-2020.pdf
http://wrap.warwick.ac.uk/140390/7/WRAP-Oxidative-ring-expansion-low-coordinate-palladacyclesynthesis-Chaplin-2020.pdf
Publikováno v:
Organic letters. 20(18)
The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl- antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::82779fdd3967d82d0681df980513b17f
https://pubmed.ncbi.nlm.nih.gov/30192552
https://pubmed.ncbi.nlm.nih.gov/30192552
