Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Matko Orhanovic"'
Preparation, Characterization, and Aquation Kinetics of Pyridine N ‐Oxide Complexes of Chromium(III)
Publikováno v:
European Journal of Inorganic Chemistry. 2006:2894-2899
A series of (H2O)5Cr(X-pyO)3+ ions (pyO = pyridine N-oxide, X = H, 3-CH3, 4-CH3, 4-OCH3, 4-NO2) were prepared by the reduction of the corresponding pyridine N-oxide adducts of diperoxochromium(VI) species with acidic ferrous perchlorate. The (H2O)5Cr
Publikováno v:
Inorganica Chimica Acta. :280-284
The complexes L 1 (H 2 O)CrR 2+ (L 1 =[14]aneN 4 ) undergo homolytic chromiumcarbon bond cleavage in aqueous solutions (R=CHMe 2 , k =0.003 s −1 ; CH(Me)(Et), 0.013; CH(Et) 2 , 0.047) much more rapidly than the complexes in the aqua series, (H 2
Publikováno v:
Environmental sciencetechnology. 17(9)
Determination du taux de reaction du pyrene, phenanthrene et du benzo [a] pyrene avec l'ozone dans l'eau par la methode spectrometrique stopped flow
Publikováno v:
Inorganic Chemistry. 32:5886-5888
The reduction of alkyl halides is a subject that has been of mechanistic interest for over two decades. Much effort has been expanded in distinguishing among electron-transfer, atom-transfer, and oxidative-addition mechanisms. With the new (H[sub 2]O
Publikováno v:
Inorganic Chemistry. 30:481-483
A series of (imidazole)pentaaquachromium(III) complexes, (H{sub 2}O){sub 5}Cr(Im-X,Y){sup 3+} were prepared and characterized in acidic aqueous solution. These complexes are reduced by {sup {center dot}}C(CH{sub 3}){sub 2}OH radicals with rate consta
The reduction of pyridine N-oxides by 1-hydroxy-1-methylethyl radicals, •CMe2OH, is acid-dependent, in accord with the greater reducibility of protonated pyridine N-oxides. The respective rate constants for the unprotonated (kR0) and protonated (kR
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1a306355d91f510be8e588b064d3d86
https://www.bib.irb.hr/1676
https://www.bib.irb.hr/1676
Publikováno v:
ChemInform. 21
The rates of electron transfer from {sup {sm bullet}}C(CH{sub 3}){sub 2}OH to a series of imidazolium ions and to a series of (NH{sub 3}){sub 5}Co(X-Im){sup 3+} complexes have been measured. A kinetic competition method based on the homolytic scissio
Preparation, Characterization, and Aquation Kinetics of Pyridine N-Oxide Complexes of Chromium(III).
Publikováno v:
European Journal of Inorganic Chemistry; Jul2006, Vol. 2006 Issue 14, p2894-2899, 6p
Publikováno v:
Inorganic Chemistry. 13:57-60
Publikováno v:
Inorganic Chemistry. 26:3249-3253
The kinetics of oxidation of Ru(NH/sub 3/)/sub 6//sup 2 +/ and of (NH/sub 3/)/sub 5/Ru(NC/sub 5/H/sub 4/X)/sup 2 +/, X = H, 3-Cl, 4-CH/sub 3/, 4-C(CH/sub 3/)/sub 3/, and 4-N(CH/sub 3/)/sub 2/, by /sup ./C(CH/sub 3/)/sub 2/OH (k/sub R/) and by Co(bpy)