Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Mathilde Appel"'
Publikováno v:
Journal of Organometallic Chemistry. 322:77-88
The complexes (η 5 -C 5 H 5 )(OC) 3 MX (M Mo, W; X OSO 2 F, OSO 2 CF 3 , OSO 2 C 6 F 13 , OC(O)C 3 F 7 ), (OC) 5 MX (M Mn, Re; X OSO 2 C 6 F 13 , OC(O) 3 F 7 , OC(O)C 7 F 15 ) are obtained from their alkyl complexes and the correspon
Autor:
Mathilde Appel, Wolfgang Beck
Publikováno v:
Journal of Organometallic Chemistry. 319:C1-C4
Zusammenfassung The coordination of the tetrafluoroborate ligand in Cp(OC)2(R3P)MoFBF3 (R = Me, Et) is confirmed by a 19F NMR study (at −80°C), the spectrum shows a double quartet for the metal-coordinated fluorine atom and a doublet for the termi
Publikováno v:
Chemische Berichte. 120:1087-1089
Pentacarbonyl(tetrafluoroborato)rhenium setzt sich mit Trimethyl(1-propinyl)stannan zu (OC)5Re–CC–CH3 (1), mit Ethinyltrimethylsilan zum σ,π-Ethinid-verbruckten Komplex [(OC)5Re(μ-η1,η2-CCH)Re(CO)5]+ BF–4 (2) um. Aus 2 und Natriumethanolat